Triphenylstibine oxide

Suppliers

Names

[ CAS No. ]:
4756-75-6

[ Name ]:
Triphenylstibine oxide

[Synonym ]:
diphenylstiborylbenzene
Stibine, triphenyl-, oxide
TriphenylantiMony Oxide
EINECS 225-292-9
Triphenylstibine oxide

Chemical & Physical Properties

[ Molecular Formula ]:
C18H15OSb

[ Molecular Weight ]:
369.071

[ Exact Mass ]:
368.016113

[ PSA ]:
17.07000

[ LogP ]:
4.34160

[ Storage condition ]:
Refrigerator

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
WJ0900000
CHEMICAL NAME :
Stibine oxide, triphenyl-
CAS REGISTRY NUMBER :
4756-75-6
LAST UPDATED :
199712
DATA ITEMS CITED :
27
MOLECULAR FORMULA :
C18-H15-O-Sb
MOLECULAR WEIGHT :
369.08
WISWESSER LINE NOTATION :
O-SB-R&R&R

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
180 mg/kg
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#01710 *** REVIEWS *** ACGIH TLV-TWA 0.5 mg(Sb)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.5 mg(Sb)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,15,1971 OSHA PEL (Gen Indu):8H TWA 0.5 mg(Sb)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.5 mg(Sb)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.5 mg(Sb)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.5 mg(Sb)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-ARAB Republic of Egypt:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-AUSTRALIA:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-AUSTRIA:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-BELGIUM:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-DENMARK:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-FINLAND:.TWA (0.5 mg(Sb)/m3) JAN 1993 OEL-FRANCE:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-GERMANY:TWA 0.5 mg(Sb)/m3 (total dust) JAN 1993 OEL-HUNGARY:STEL 0.5 mg(Sb)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-POLAND:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-RUSSIA:TWA 0.2 mg(Sb)/m3;STEL 0.5 mg(Sb)/m3 JAN 1993 OEL-SWEDEN:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-SWITZERLAND:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-TURKEY:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.5 mg(Sb)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO ANTIMONY-air:10H TWA 0.5 mg(Sb)/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992

Safety Information

[ Risk Phrases ]:
20/22-51/53

[ Safety Phrases ]:
22-36/37/39

[ RIDADR ]:
UN 3282

[ RTECS ]:
WJ0900000

[ Packaging Group ]:
III

Precursor & DownStream

Precursor

  • Triphenylstibine
  • Stibonium,tetraphenyl-, hydroxide (8CI,9CI)
  • Hydrogen peroxide
  • tert-Butyl Hydroperoxide
  • tetraphenylantimony phthalate

DownStream

  • Methylrhenium trioxide
  • 3-methyl-1,3-oxazolidine-2-thione

Related Compounds

  • Triphenylstibine
  • Butylene oxide, polypropylene glycol polymer
  • Aluminum oxide, basic
  • Magnesium oxide phosphate
  • Iron oxide brown
  • Methoxymethyldiphenylphosphine oxide
  • 1-{2-[6-(1H-1,2,4-triazol-1-yl)pyridin-3-yl]ethyl}cyclopropan-1-amine
  • 3-Amino-3-(1-phenylprop-1-en-2-yl)cyclobutan-1-ol
  • Tert-butyl 3-(hydroxymethyl)-5-phenylthiomorpholine-4-carboxylate
  • 5-(1-Amino-2,2-difluoroethyl)-2-nitrophenol
  • 3-(2-Chloroquinolin-3-yl)-1,1,1-trifluoropropan-2-amine
  • 2-(1-{6,6-Dimethylbicyclo[3.1.1]heptan-2-yl}cyclopropyl)acetic acid
  • tert-butyl N-(2-{[1-(methylamino)cyclopropyl]methyl}-5-(trifluoromethyl)phenyl)carbamate
  • 3-hydroxy-1-(1-methyl-1H-pyrazol-3-yl)cyclobutane-1-carboxylic acid
  • Methyl 2-{[(tert-butoxy)carbonyl]amino}-3-hydroxy-4-methoxybenzoate
  • tert-butyl N-{2-hydroxy-3-methoxy-5-[(sulfamoyloxy)methyl]phenyl}carbamate
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