Diphenylmaleic anhydride

Names

[ Name ]:
Diphenylmaleic anhydride

[Synonym ]:
2,5-Furandione, 3,4-diphenyl-
Diphenylmaleic anhydride
2,3-DiphenylMaleic Anhydride
EINECS 225-370-2
3,4-diphenylfuran-2,5-dione
3,4-Diphenyl-2,5-furandione
MFCD00005521

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
437.1±45.0 °C at 760 mmHg

[ Melting Point ]:
153-157ºC

[ Molecular Formula ]:
C₁₆H₁₀O₃

[ Molecular Weight ]:
250.249

[ Flash Point ]:
215.4±25.9 °C

[ Exact Mass ]:
250.062988

[ PSA ]:
43.37000

[ LogP ]:
3.29

[ Appearance of Characters ]:
Crystalline Powder or Powder | Yellow to dark yellow

[ Vapour Pressure ]:
0.0±1.0 mmHg at 25°C

[ Index of Refraction ]:
1.642

[ Water Solubility ]:
DMF: soluble

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2917399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Phenylacetic acid
Phenylglyoxylic acid
3,4-diphenyl-5H-furan-2-one
diethyl (Z)-2,3-diphenylmaleate
2-bromo-N-methoxy-2-phenylacetamide
Ethyl oxophenylacetate
Phenylacetyl chloride
Carbon dioxide
Diphenylacetylene

DownStream

3,4-Diphenyl-1h-pyrrole-2,5-dione
4,5-Diphenyl-3,6-dihydro-1,2-dithiine
4,5-Diphenyl-3,6-dihydro-1,2-dithiine 1-oxide
phenanthro[9,10-c]furan-1,3-dione
1-methyl-3,4-diphenylpyrrole-2,5-dione
3,4-diphenyl-5H-furan-2-one
1,5-diphenyl-3,6-dioxabicyclo[3.1.0]hexane-2,4-dione
2,3-diphenylbut-2-ene-1,4-diol
benzoic acid

Customs

[ HS Code ]: 2917399090

[ Summary ]:
2917399090 aromatic polycarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles

Sensitive enantiomeric separation of aliphatic and aromatic amines using aromatic anhydrides as nonchiral derivatizing agents.

J. Chromatogr. A. 666 , 485-491, (1994)

New pre-column derivatizing reagents: phthalic anhydride, 3-nitrophthalic anhydride, diphenic anhydride, 1,8-naphthalic anhydride and diphenylmaleic anhydride have been developed for resolving chiral ...

Comparison of the chiral separation of amino-acid derivatives by a teicoplanin and RN-beta-CD CSPs using waterless mobile phases: Factors that enhance resolution.

Chirality 16 , 318-330, (2004)

A variety of compounds containing amines (i.e., amino acids, amino alcohols, etc.) were chemically derivatized with a variety of electrophilic tagging reagents to elucidate the chiral recognition site...

Methacrylic anhydride
Perfluorooctanoic anhydride
DIFRUCTOSE ANHYDRIDE III
2,2,3,3,4,4-Hexafluoropentanedioic Anhydride
acetic anhydride carbanion
methanesulfinic anhydride
3-(Chloromethyl)-2,5-dimethyloxolane-3-carbaldehyde
2-{[4-(hydroxymethyl)-5-(methoxymethyl)-1H-1,2,3-triazol-1-yl]methyl}phenol
1-benzyl-4-(chloromethyl)-5-(1-methoxyethyl)-1H-1,2,3-triazole
4-(chloromethyl)-1-[(2-fluorophenyl)methyl]-5-methyl-1H-1,2,3-triazole
4-(chloromethyl)-5-methyl-1-[(2-methylphenyl)methyl]-1H-1,2,3-triazole
4-(chloromethyl)-1-[(3-fluorophenyl)methyl]-5-methyl-1H-1,2,3-triazole
1-[(2-bromophenyl)methyl]-4-(chloromethyl)-5-methyl-1H-1,2,3-triazole
1-[(2-bromophenyl)methyl]-4-(chloromethyl)-5-(difluoromethyl)-1H-1,2,3-triazole
4-(chloromethyl)-1-[(3-methylphenyl)methyl]-5-propyl-1H-1,2,3-triazole
4-{[4-(chloromethyl)-5-(difluoromethyl)-1H-1,2,3-triazol-1-yl]methyl}phenol

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