Glycine,N-(2-hydroxybenzoyl)-

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Names

[ CAS No. ]:
487-54-7

[ Name ]:
Glycine,N-(2-hydroxybenzoyl)-

[Synonym ]:
2-Hydroxyhippuric acid
EINECS 207-661-6
2-[(2-hydroxybenzoyl)amino]acetic acid
MFCD00002695

Chemical & Physical Properties

[ Density]:
1.401 g/cm3

[ Boiling Point ]:
489.8ºC at 760 mmHg

[ Melting Point ]:
164-169 °C

[ Molecular Formula ]:
C9H9NO4

[ Molecular Weight ]:
195.17200

[ Flash Point ]:
250ºC

[ Exact Mass ]:
195.05300

[ PSA ]:
86.63000

[ LogP ]:
0.59750

[ Vapour Pressure ]:
2.08E-10mmHg at 25°C

[ Storage condition ]:
Store at 0°C

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
MR8160000
CHEMICAL NAME :
Hippuric acid, o-hydroxy-
CAS REGISTRY NUMBER :
487-54-7
BEILSTEIN REFERENCE NO. :
2213833
LAST UPDATED :
199612
DATA ITEMS CITED :
5
MOLECULAR FORMULA :
C9-H9-N-O4
MOLECULAR WEIGHT :
195.19
WISWESSER LINE NOTATION :
QV1MVR BQ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
3 gm/kg
TOXIC EFFECTS :
Behavioral - convulsions or effect on seizure threshold Cardiac - change in rate Lungs, Thorax, or Respiration - other changes
REFERENCE :
AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. (Heymans Institute of Pharmacology, De Pintelaan 185, B-9000 Ghent, Belgium) V.4- 1898- Volume(issue)/page/year: 38,9,1930
TYPE OF TEST :
LD - Lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
>1 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
FRPSAX Farmaco, Edizione Scientifica. (Casella Postale 227, 27100 Pavia, Italy) V.8-43 1953-88 For publisher information, see FRMCE8 Volume(issue)/page/year: 30,399,1975
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
600 mg/kg
TOXIC EFFECTS :
Behavioral - convulsions or effect on seizure threshold Cardiac - change in rate Lungs, Thorax, or Respiration - other changes
REFERENCE :
AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. (Heymans Institute of Pharmacology, De Pintelaan 185, B-9000 Ghent, Belgium) V.4- 1898- Volume(issue)/page/year: 38,9,1930
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Bird - pigeon
DOSE/DURATION :
5730 mg/kg
TOXIC EFFECTS :
Behavioral - convulsions or effect on seizure threshold Cardiac - change in rate Lungs, Thorax, or Respiration - other changes
REFERENCE :
AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. (Heymans Institute of Pharmacology, De Pintelaan 185, B-9000 Ghent, Belgium) V.4- 1898- Volume(issue)/page/year: 38,9,1930
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Bird - pigeon
DOSE/DURATION :
2080 mg/kg
TOXIC EFFECTS :
Behavioral - convulsions or effect on seizure threshold Cardiac - change in rate Lungs, Thorax, or Respiration - other changes
REFERENCE :
AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. (Heymans Institute of Pharmacology, De Pintelaan 185, B-9000 Ghent, Belgium) V.4- 1898- Volume(issue)/page/year: 38,9,1930

Safety Information

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
S24/25

[ RIDADR ]:
NONH for all modes of transport

[ RTECS ]:
MR8160000

[ HS Code ]:
2924299090

Precursor & DownStream

Precursor

  • benzyl 2-(2-hydroxybenzamido)acetate
  • N-(2-Hydroxybenzoyl)glycine methyl ester
  • Salicylic acid
  • 2-Methoxybenzoic acid
  • 2-azidoacetoxy-benzoic acid
  • N-(2-amino-2-oxoethyl)-2-hydroxy-Benzamide
  • Benzoic acid,2-[(methoxycarbonyl)oxy]-
  • Benzyl salicylate
  • N-(2-Methoxybenzoyl)glycine methyl ester

DownStream

  • Acetic acid,hydroxy[(2-hydroxybenzoyl)amino]- (9CI)
  • Salicylamide
  • 2,4,6-Tribromophenol
  • Glycine
  • Salicylic acid
  • N-(2-Hydroxybenzoyl)glycine methyl ester

Customs

[ HS Code ]: 2924299090

[ Summary ]:
2924299090. other cyclic amides (including cyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%


Related Compounds

  • Glycine,N-[N-[N-(2-hydroxybenzoyl)glycyl]phenylalanyl]-, methyl ester (9CI)
  • Glycine, N-(2,4-dimethylphenyl)-, methyl ester
  • Glycine, N-[2-[(carboxymethyl)amino]ethyl]-N-(2-hydroxyethyl)-, N-coco acyl deriv. disodium salts
  • Glycine, N-[2-[(2-hydroxyethyl)amino]ethyl]-, N-C3-11-acyl derivs., monosodium salts
  • Glycine, N-[2-[(2-hydroxyethyl)amino]ethyl]-, N-coco acyl derivs., monosodium salts
  • Glycine, N-(2-methoxyethyl)-N-methyl
  • 2-(2-Methylpiperidin-1-yl)pyrimidine-4-carboxylic acid
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 2-Methyl-6-(trifluoromethyl)piperidine-3-carboxylic acid
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine