DICHLORODIPHENOXYMETHANE

Names

[ CAS No. ]:
4885-03-4

[ Name ]:
DICHLORODIPHENOXYMETHANE

[Synonym ]:
Phosgene diphenyl acetal
1,1-dichloro-1,1-diphenoxymethane
1,1-dichlorodiphenoxymethane
dichlorodiphenoxymethane
MFCD00087870
diphenoxydichloromethane

Chemical & Physical Properties

[ Density]:
1.37g/cm3

[ Boiling Point ]:
665.4ºC at 760mmHg

[ Melting Point ]:
39-44ºC(lit.)

[ Molecular Formula ]:
C13H10Cl2O2

[ Molecular Weight ]:
269.12300

[ Flash Point ]:
356.2ºC

[ Exact Mass ]:
268.00600

[ PSA ]:
18.46000

[ LogP ]:
4.23330

[ Index of Refraction ]:
1.587

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C: Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
26-36/37/39-45

[ RIDADR ]:
UN 1759 8/PG 2

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Diphenyl carbonate
  • Diphenoxymethane

DownStream

  • 1,4,6,9-tetraoxaspiro[4.4]nonane
  • Diphenyl cyanocarbonimidate
  • Tetraethyl orthocarbonate
  • 1,5,7,11-tetraoxaspiro[5.5]undecane
  • 2-piperidinobenzoxazole
  • phenyl 2,2-dimethyl-3-oxopropanoate
  • triphenoxymethoxybenzene
  • 3,9-Dimethylidene-1,5,7,11-tetraoxaspiro5.5undecane

Articles

Iodine-Catalyzed Synthesis of Spiroorthocarbonates under Neutral Conditions. Rahimizadeh M, et al.

ChemInform 41(1) , i, (2010)

Synthesis and mass spectral fragmentations of new spiro heterocycles. Rahimizadeh M, et al.

Chin. Chem. Lett. 18(6) , 689-693, (2007)

The Reactions of Methyl-and n-Butyllithium with Dichloromethyl Methyl Ether and Dichlorodiphenoxymethane. McDonald RN and Krueger.

J. Org. Chem. 30(12) , 4372-4375, (1965)


More Articles