Methyl 3-phenyl-2-propynoate

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Names

[ CAS No. ]:
4891-38-7

[ Name ]:
Methyl 3-phenyl-2-propynoate

[Synonym ]:
Phenylpropynoic acid methyl ester
Methyl Phenylpropiolate
Propiolic acid, 3-phenyl-, methyl ester
methyl 3-phenylprop-2-ynoate
Phenylpropargylic Acid Methyl Ester
2-Propynoic acid, 3-phenyl-, methyl ester
Methyl 3-phenyl-2-propynoate
MFCD00041685
Phenylpropiolic Acid Methyl Ester

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
247.9±9.0 °C at 760 mmHg

[ Melting Point ]:
26ºC

[ Molecular Formula ]:
C10H8O2

[ Molecular Weight ]:
160.169

[ Flash Point ]:
117.4±6.7 °C

[ Exact Mass ]:
160.052429

[ PSA ]:
26.30000

[ LogP ]:
3.19

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.546

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319

[ Precautionary Statements ]:
P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2916399090

Precursor & DownStream

Precursor

  • 3-Phenylpropiolic acid
  • methyl iodide
  • Iodobenzene
  • methylpropiolate
  • Methyl chloroformate
  • Phenylacetylene
  • Methanol
  • diazomethane
  • carbon monoxide
  • 3-Phenyl-2-propyn-1-ol

DownStream

  • methyl 3,3-dimethyl-5-phenylpyrazole-4-carboxylate
  • methyl 5,5-dimethyl-4-phenylpyrazole-3-carboxylate
  • Methyl (2Z)-3-phenylacrylate
  • Methyl cinnamate
  • Methyl 3-phenylpropanoate
  • Methyl 2,5-diphenyl-1,3-oxazole-4-carboxylate
  • methyl 2-phenylbicyclo[2.2.1]hepta-2,5-diene-3-carboxylate
  • Quinoxaline,2,3-dimethyl-
  • Quinoxaline,2,3-dimethyl-, 4-oxide
  • dimethyl 2,11-diphenyldipyrrolo[1,2-a:2',1'-c]quinoxaline-3,10-dicarboxylate

Customs

[ HS Code ]: 2916399090

[ Summary ]:
2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Regio- and enantioselective intermolecular rhodium-catalyzed [2+2+2] carbocyclization reactions of 1,6-enynes with methyl arylpropiolates.

J. Am. Chem. Soc. 127(36) , 12466-7, (2005)

Transition metal-catalyzed [m+n+o] carbocyclization reactions provide powerful methods for the construction of complex polycyclic systems that are generally not accessible through classical pericyclic...

Steric effects on reactivity in silicon chemistry. Cartledge FK.

Organometallics 2(3) , 425-430, (1983)

Preparation and Structures of Methyl Phenylpropiolate-Iron Carbonyl Complexes. A New Dicarbonyl-p-cyclopentadienyloxy-s-vinyliron Compound. Dahl LF, et al.

J. Am. Chem. Soc. 88(3) , 446-452, (1966)


More Articles

Related Compounds

  • methyl 3-phenyl-2-(dimethylsilyl)propanoate
  • methyl 3-phenyl-2,3-dihydro-1H-pyrrole-1-carboxylate
  • 5-methyl-3-phenyl-2-phthalazin-1-yl-4H-pyrazol-3-ol
  • 1-methyl-3-phenyl-2-sulfanylidene-quinazolin-4-one
  • 2-methyl-3-phenyl-2,3-dihydroinden-1-one
  • 3-methyl-3-phenyl-2-butanone oxime
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 2-Isopropyl-2-phenylpropane-1,3-diol
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide