2-Bromo-4-methylpyridine

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Names

[ CAS No. ]:
4926-28-7

[ Name ]:
2-Bromo-4-methylpyridine

[Synonym ]:
Pyridine, 2-bromo-4-methyl-
2-Bromo-4-picoline
2-Br-4-Me-pyridine
4-Methyl-2-bromopyridine
MFCD00082590
2-bromo-4-methyl pyridine
2-Bromo-4-methylpyridine

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
219.8±20.0 °C at 760 mmHg

[ Melting Point ]:
218 - 228ºC

[ Molecular Formula ]:
C6H6BrN

[ Molecular Weight ]:
172.02

[ Flash Point ]:
86.7±21.8 °C

[ Exact Mass ]:
170.968353

[ PSA ]:
12.89000

[ LogP ]:
1.99

[ Vapour Pressure ]:
0.2±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.553

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn:Harmful

[ Risk Phrases ]:
R20/21/22;R36/37/38

[ Safety Phrases ]:
S26-S36-S36/37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2933399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Aminopicoline
  • 4-Picoline
  • acetyl hypofluorite

DownStream

  • 6,6'-Dimethyl-2,2'-bipyridine
  • 4,4'-Dimethyl-2,2'-bipyridine
  • 4,6'-dimethyl-2,2'-bipyridine
  • 4-Methyl-2-phenylpyridine
  • (4-Methyl-2-pyridinyl)boronic acid
  • 1-(4-Methyl-2-pyridinyl)ethanone
  • 2-Fluoro-4-methylpyridine
  • 2-BROMO-4-PYRIDINE ACETIC ACID
  • 2-Mercapto-4-methylpyridine
  • 2-(4-CHLORO-PHENYL)-4-METHYL-PYRIDINE

Customs

[ HS Code ]: 2933399090

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Total synthesis of the ocular age pigment A2-E: a convergent pathway. Ren R X-F, et al.

J. Am. Chem. Soc. 119(15) , 3619-20, (1997)

Pd (0)-Catalyzed cross-coupling reactions of 2-indolylzinc halides. A convenient route to indolo [2, 3-a] quinolizidines. Amat M, et al.

ARKIVOC 73 , 82, (2002)

Blue Emitting Cationic Iridium Complexes Containing Two Substituted 2-Phenylpyridine and One 2, 2'-Biimidazole for Solution-Processed Organic Light-Emitting Diodes (OLEDs). Yun S-J, et al.

Bull. Korean Chem. Soc. 33(11) , 3645-50, (2012)


More Articles

Related Compounds

  • 5-Amino-2-bromo-4-methylpyridine
  • 2-Bromo-4-methylpyridine-3-carbonitrile
  • 2-bromo-4-methylpyridine-3-carboxylic acid
  • ethyl 2-bromo-4-methylpyridine-3-carboxylate
  • 2-Bromo-4-methylpyridine-3-boronic acid pinacol ester
  • 2-bromo-4-fluoro-5-methylpyridine
  • 1-[1-(difluoromethyl)-1H-pyrazol-5-yl]-N-[(1,3-dimethyl-1H-pyrazol-5-yl)methyl]methanamine
  • 1-(1-ethyl-1H-pyrazol-3-yl)-N-[(1-ethyl-1H-pyrazol-4-yl)methyl]methanamine
  • 1-(1-ethyl-1H-pyrazol-5-yl)-N-(3-methoxybenzyl)methanamine
  • [(1,4-dimethyl-1H-pyrazol-5-yl)methyl](3-morpholin-4-ylpropyl)amine
  • 1-(1-ethyl-3-methyl-1H-pyrazol-4-yl)-N-[(1-ethyl-1H-pyrazol-3-yl)methyl]methanamine
  • 1-cyclopentyl-N-[(4-fluorophenyl)methyl]pyrazol-4-amine;hydrochloride
  • 1-cyclopentyl-N-(2-furylmethyl)-1H-pyrazol-4-amine
  • 1-(1-ethyl-1H-pyrazol-3-yl)-N-[(1-propyl-1H-pyrazol-4-yl)methyl]methanamine
  • 1-cyclopentyl-N-[(3-fluorophenyl)methyl]pyrazol-4-amine;hydrochloride
  • 1-(1-ethyl-1H-pyrazol-5-yl)-N-(2-methoxybenzyl)methanamine
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