Solvent Orange 3

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Names

[ CAS No. ]:
495-54-5

[ Name ]:
Solvent Orange 3

[Synonym ]:
Chrysoidin A
azoaniline
Oil Orange Y
chrysoidine
EINECS 207-803-7
4-phenylazo-m-phenylenediamine
Chrysoidine Base
Oranz zasadita 2
Azohel
2,4-Diamino-azobenzol
azodianiline
Chrysoidine G
SOLVENT ORANGE 3
Fat Brown GG
4-Phenylazo-m-phenylendiamin

Chemical & Physical Properties

[ Density]:
1.23 g/cm3

[ Boiling Point ]:
431.6ºC at 760 mmHg

[ Molecular Formula ]:
C12H12N4

[ Molecular Weight ]:
212.25000

[ Flash Point ]:
214.8ºC

[ Exact Mass ]:
212.10600

[ PSA ]:
76.76000

[ LogP ]:
4.42880

[ Vapour Pressure ]:
1.13E-07mmHg at 25°C

[ Index of Refraction ]:
1.65

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
ST3325000
CHEMICAL NAME :
m-Phenylenediamine, 4-(phenylazo)-
CAS REGISTRY NUMBER :
495-54-5
BEILSTEIN REFERENCE NO. :
0745990
LAST UPDATED :
199710
DATA ITEMS CITED :
10
MOLECULAR FORMULA :
C12-H12-N4
MOLECULAR WEIGHT :
212.28
WISWESSER LINE NOTATION :
ZR CZ DNUNR

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1650 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1667 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1667 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :
Unscheduled DNA synthesis
TEST SYSTEM :
Rodent - rat Liver
DOSE/DURATION :
500 ng/well
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 240,227,1990 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M4477 No. of Facilities: 22 (estimated) No. of Industries: 2 No. of Occupations: 2 No. of Employees: 759 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M4477 No. of Facilities: 2 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 12 (estimated) No. of Female Employees: 7 (estimated)

Safety Information

[ Safety Phrases ]:
S24/25

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • m-Phenylenediamine
  • benzenediazonium
  • Benzene-1,3-diamine dihydrochloride

DownStream

  • 2-PHENYL-2H-BENZOTRIAZOL-5-YLAMINE
  • 2-Phenyl-1H-benzo[d]imidazole
  • 4-[(2,4-diaminophenyl)diazenyl]benzenesulfonic acid
  • Benzenediazonium chloride
  • 6-amino-2-phenyl-1,2,4-benzotriazin-3-one
  • 1,2,4-Benzenetriamine

Related Compounds

  • Solvent Orange 3
  • Solvent Orange 45
  • Solvent orange 55
  • Solvent Orange 75
  • Solvent Orange 63
  • Solvent Orange 56
  • Cobaltate(1-), [2,4-dihydro-4-[[2-hydroxy-5-(methylsulfonyl)phenyl]azo]-5-methyl-2-phenyl-3H-pyrazol-3-onato(2-)][N-[7-hydroxy-8-[[2-hydroxy-5-(methylsulfonyl)phenyl]azo]-1-naphthalenyl]acetamidato(2-)]-, sodium
  • Chromate(3-), bis[4-[2-[4,5-dihydro-3-methyl-5-(oxo-kappaO)-1-phenyl-1H-pyrazol-4-yl]diazenyl-kappaN1]-3-(hydroxy-kappaO)-7-nitro-1-naphthalenesulfonato(3-)]-, hydrogen (1:3)
  • Chromate(3-), bis[4-[4,5-dihydro-4-[2-[2-(hydroxy-kappaO)-5-methyl-3-nitrophenyl]diazenyl-kappaN1]-3-methyl-5-(oxo-kappaO)-1H-pyrazol-1-yl]benzenesulfonato(3-)]-, hydrogen (1:3)
  • Cobaltate(2-), [2,4-dihydro-4-[(2-hydroxy-5-nitrophenyl)azo]-5-methyl-2-phenyl-3H-pyrazol-3-onato(2-)][2-[[[4-hydroxy-3-[[2-(phenylamino)-1-naphthalenyl]azo]phenyl]sulfonyl]amino]benzoato(3-)]-, sodium hydrogen
  • Cobaltate(2-), [2,4-dihydro-4-[(2-hydroxy-5-nitrophenyl)azo]-5-methyl-2-phenyl-3H-pyrazol-3-onato(2-)][3-hydroxy-4-[(2-hydroxy-1-naphthalenyl)azo]-7-nitro-1-naphthalenesulfonato(3-)]-, dihydrogen
  • Chromate(3-), bis[5-[2-[5-chloro-2-(hydroxy-kappaO)phenyl]diazenyl-kappaN1]-4-hydroxy-6-(hydroxy-kappaO)-2-naphthalenesulfonato(3-)]-, hydrogen (1:3)
  • Chromate(3-), bis[5-chloro-2-(hydroxy-kappaO)-3-[2-[1-(hydroxy-kappaO)-5-hydroxy-2-naphthalenyl]diazenyl-kappaN1]benzenesulfonato(3-)]-, hydrogen (1:3)
  • Chromate(3-), bis[5-chloro-2-(hydroxy-kappaO)-3-[2-[2-(hydroxy-kappaO)-1-naphthalenyl]diazenyl-kappaN1]benzenesulfonato(3-)]-, hydrogen (1:3)
  • Chromate(3-), bis[6-(amino-kappaN)-5-[2-[2-(hydroxy-kappaO)-4-nitrophenyl]diazenyl-kappaN1]-1-naphthalenesulfonato(3-)]-, hydrogen (1:3)
  • Chromate(3-), bis[7-amino-4-(hydroxy-kappaO)-3-[2-[2-(hydroxy-kappaO)-4-nitrophenyl]diazenyl-kappaN1]-2-naphthalenesulfonato(3-)]-, hydrogen (1:3)
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