2-Bromo-4-fluorophenol

Names

[ CAS No. ]:
496-69-5

[ Name ]:
2-Bromo-4-fluorophenol

[Synonym ]:
2-Brom-4-fluor-phenol
5-fluorobiphenyl-2-ol
QR DF BE
2-bromo-4-fluoro-phenol
4-fluoro-2-bromophenol
MFCD00010614
2-Bromo-4-fluorophenol
Phenol, 2-bromo-4-fluoro-

Chemical & Physical Properties

[ Density]:
1.8±0.1 g/cm3

[ Boiling Point ]:
260.6±0.0 °C at 760 mmHg

[ Melting Point ]:
43-45 °C(lit.)

[ Molecular Formula ]:
C₆H₄BrFO

[ Molecular Weight ]:
191.00

[ Flash Point ]:
85.0±0.0 °C

[ Exact Mass ]:
189.942947

[ PSA ]:
20.23000

[ LogP ]:
2.75

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.576

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn:Harmful

[ Risk Phrases ]:
R22;R36/37/38

[ Safety Phrases ]:
S26-S36/37/39

[ RIDADR ]:
3276

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ HS Code ]:
2908199090

Precursor & DownStream

Precursor

4-Fluorophenol
2-Bromo-4-fluoro-1-methoxybenzene
4-Fluoroaniline
4-tert-Butylphenol

DownStream

2-Bromo-4-fluoro-1-methoxybenzene
5-Fluoro-2-hydroxybenzaldehyde
2-Bromo-1-(2,2-diethoxyethoxy)-4-fluorobenzene
2-Bromo-4-fluoro-5-nitrophenol
(4-Fluoro-2-hydroxyphenyl)boronic acid
Methyl 2-bromo-4-fluorobenzoate
2-bromo-1-ethoxy-4-fluorobenzene
3-bromo-5-fluoro-2-hydroxybenzaldehyde
4H-1-Benzopyran-4-one,6-fluoro-2-phenyl-
2-benzylidene-5-fluorobenzofuran-3(2H)-one

Customs

[ HS Code ]: 2908199090

[ Summary ]:
HS: 2908199090. derivatives of polyphenols or phenol-alcohols containing only halogen substituents and their salts. VAT:17.0%. tax rebate rate:9.0%. supervision conditions:None. MFN tariff:5.5%. general tariff:30.0%

Articles

Metal-free oxidative fluorination of phenols with [18F]fluoride.

Angew. Chem. Int. Ed. Engl. 51(27) , 6733-7, (2012)

Structure-activity relationships of 6-(aminomethylphenoxy)-benzoxaborole derivatives as anti-inflammatory agent.

Bioorg. Med. Chem. Lett. 23(6) , 1680-3, (2013)

A series of novel 6-(aminomethylphenoxy)benzoxaborole analogs was synthesized for the investigation of the structure-activity relationship of the inhibition of TNF-alpha, IL-1beta, and IL-6, from lipo...

5-Amino-2-bromo-4-fluorophenol
O-Acetyl-2-bromo-4-fluorophenol
2-Bromo-4-chloro-6-fluorophenol
2-Bromo-5-chloro-4-fluorophenol
2-Bromo-6-chloro-4-fluorophenol
2-bromo-4-iodophenol
(1S)-2,2,2-trifluoro-1-(quinolin-7-yl)ethan-1-ol
6-(2-Bromomethyl-pyrimidin-4-yloxy)-naphthalene-1-carboxylic acid methyl ester
(1s)-2,2,2-Trifluoro-1-(thiophen-3-yl)ethan-1-ol
5-[1-[[(Phenylmethoxy)carbonyl]amino]ethyl]-2-thiophenecarboxylic acid
(1R)-2,2,2-trifluoro-1-(5-methylthiophen-2-yl)ethan-1-ol
Benzeneethanol, I+/--3-buten-1-yl-4-fluoro-I(2),I(2)-dimethyl-
(1S)-1-(2-ethoxyphenyl)-2,2,2-trifluoroethan-1-ol
3-(3-Methoxybenzoyl)-1,2,3,6-tetrahydroazepino[4,5-b]indole-5-carboxylic acid isopropyl ester
(2S)-3-(4-aminopyridin-3-yl)-1,1,1-trifluoropropan-2-ol
2-(3-Bromo-5-fluorophenyl)pyrimidin-4-amine

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