(11bS)-N,N-Bis[(R)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
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Names
[ CAS No. ]:
497883-22-4
[ Name ]:
(11bS)-N,N-Bis[(R)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
[Synonym ]:
N,N-Bis[(1R)-1-phenylethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, N,N-bis[(1R)-1-phenylethyl]-
MFCD08561138
(11bS)-N,N-Bis[(R)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
Chemical & Physical Properties
[ Boiling Point ]:
710.7±63.0 °C at 760 mmHg
[ Melting Point ]:
102-103°C
[ Molecular Formula ]:
C36H30NO2P
[ Molecular Weight ]:
539.603
[ Flash Point ]:
383.6±33.7 °C
[ Exact Mass ]:
539.201416
[ LogP ]:
10.33
[ Vapour Pressure ]:
0.0±2.3 mmHg at 25°C
Safety Information
[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
[ RIDADR ]:
NONH for all modes of transport
Articles
Org. Lett. 4 , 3835, (2002)
[formula: see text] The zinc enolates, resulting from the copper-catalyzed enantioselective conjugate addition of dialkyl zinc reagents to cyclic and acyclic enones, could be trapped, quantitatively, ...
J. Org. Chem. 70 , 7451, (2005)
[reaction: see text] The enantioselective catalytic 1,4-addition to alpha,beta-unsaturated ketimines is an unprecedented process. Herein, we document the copper-catalyzed addition of dialkylzinc reage...
Synlett , 1375, (2001)