Dixanthogen

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Names

[ CAS No. ]:
502-55-6

[ Name ]:
Dixanthogen

[Synonym ]:
diethyl dixanthogen
Auligen
Xantoscabin
thioperoxydicarbonic acid ([(HO)C(S)]2S2) diethyl ester
Aulinogen
diethyl dixanthogenate
O-ethyl (ethoxycarbothioyldisulfanyl)methanethioate
Silfasan
Herbisan
3,8-dioxa-5,6-dithiadecane-4,7-dithione
Scabicidol
Galasan
Lenisarin
Bexide
(SC(S)OEt)2
O,O-diethyl 2-dithioperoxy-1,3-dithiodicarbonate
O,O-diethyl dithiobis(thioformate)
MFCD00022144
EINECS 207-944-4
dixanthogen

Chemical & Physical Properties

[ Density]:
0.94 g/mL at 25 °C(lit.)

[ Boiling Point ]:
134 °C2 mm Hg(lit.)

[ Molecular Formula ]:
C6H10O2S4

[ Molecular Weight ]:
242.40200

[ Flash Point ]:
>230 °F

[ Exact Mass ]:
241.95600

[ PSA ]:
133.24000

[ LogP ]:
3.01060

[ Index of Refraction ]:
n20/D 1.479(lit.)

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
LQ7700000
CHEMICAL NAME :
Formic acid, dithiobis(thio-, O,O-diethyl ester
CAS REGISTRY NUMBER :
502-55-6
BEILSTEIN REFERENCE NO. :
1781595
LAST UPDATED :
199710
DATA ITEMS CITED :
10
MOLECULAR FORMULA :
C6-H10-O2-S4
MOLECULAR WEIGHT :
242.40
WISWESSER LINE NOTATION :
SUYO2&SSYUS&O2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
480 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
RREVAH Residue Reviews. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 07094) V.1- 1962- Volume(issue)/page/year: 10,97,1965
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2100 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PCOC** Pesticide Chemicals Official Compendium, Association of the American Pesticide Control Officials, Inc., 1966. (Topeka, KS) Volume(issue)/page/year: -,578,1966
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1200 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold Behavioral - changes in motor activity (specific assay)
REFERENCE :
FATOAO Farmakologiya i Toksikologiya (Moscow). For English translation, see PHTXA6 and RPTOAN. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.2- 1939- Volume(issue)/page/year: 28,230,1965
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
620 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PCOC** Pesticide Chemicals Official Compendium, Association of the American Pesticide Control Officials, Inc., 1966. (Topeka, KS) Volume(issue)/page/year: -,578,1966
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
320 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
APTOA6 Acta Pharmacologica et Toxicologica. (Copenhagen, Denmark) V.1-59, 1945-86. For publisher information, see PHTOEH Volume(issue)/page/year: 8,329,1952
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
400 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PCOC** Pesticide Chemicals Official Compendium, Association of the American Pesticide Control Officials, Inc., 1966. (Topeka, KS) Volume(issue)/page/year: -,578,1966
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Mammal - species unspecified
DOSE/DURATION :
600 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
30ZDA9 "Chemistry of Pesticides," Melnikov, N.N., New York, Springer-Verlag New York, Inc., 1971 Volume(issue)/page/year: -,180,1971

Safety Information

[ Hazard Codes ]:
Xn

[ Risk Phrases ]:
22

[ Safety Phrases ]:
S24

Synthetic Route

Precursor & DownStream

Precursor

  • Carbon disulphide
  • Ethanol
  • potassium ethylxanthate
  • Chloro(chlorosulfanyl)oxomethane
  • DI(ETHYLXANTHOGEN)TRISULFIDE
  • BIS(ETHYLXANTHOGEN) TETRASULFIDE
  • Carbonodithioic acid, O-ethyl S-[2-(4-methylphenyl)-2-oxoethyl] ester
  • dithiocarbonic acid O-ethyl ester S-(2-oxo-2-phenylethyl) ester
  • S-(2-(3,4-dimethoxyphenyl)-2-oxoethyl) O-ethyl carbonodithioate

DownStream

  • DI(ETHYLXANTHOGEN)TRISULFIDE
  • O-ethyl hydrogen dithiocarbonate
  • Thiocarbanilide
  • ETHYLCHLOROTHIOFORMATE
  • Carbamothioic acid,N-phenyl-, O-ethyl ester
  • potassium ethylxanthate
  • hydrogen sulfide
  • Sodium ethyl xanthate

Related Compounds

  • Dixanthogen
  • n-amyl dixanthogen
  • Dibutyl dixanthogen
  • sec-butyl dixanthogen
  • Diisoamyl dixanthogen
  • Diisobutyl dixanthogen
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • 3-[(Pent-4-yn-2-yl)amino]pyridine-4-carboxylic acid
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 2-(Chloromethyl)-6-(difluoromethyl)-4-fluoropyridine-3-acetic acid
  • 2-(2-Methylpropyl)imidazo[1,2-a]pyridine-7-carboxylic acid
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde