1-Chloro-3-methyl-2-butene

Suppliers

Names

[ CAS No. ]:
503-60-6

[ Name ]:
1-Chloro-3-methyl-2-butene

[Synonym ]:
1-chloro-3-methylbut-2-ene
Prenyl Chloride
1-Chloro-3-methyl-2-butene
EINECS 207-972-7
MFCD00000982
2-Butene, 1-chloro-3-methyl-

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
109.0±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C5H9Cl

[ Molecular Weight ]:
104.578

[ Flash Point ]:
13.3±0.0 °C

[ Exact Mass ]:
104.039276

[ LogP ]:
2.72

[ Vapour Pressure ]:
29.6±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.431

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H315-H319-H335

[ Precautionary Statements ]:
P210-P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F:Flammable;Xi:Irritant;

[ Risk Phrases ]:
R11;R36/37/38

[ Safety Phrases ]:
S16-S26-S27-S36/37/39

[ RIDADR ]:
UN 1993 3/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3

[ HS Code ]:
2903299090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 3-Methyl-2-buten-1-ol
  • 2-Methyl-3-buten-2-ol
  • isoprene
  • (E)-oct-4-en-3-one
  • 3-CHLORO-3-METHYL-1-BUTENE
  • Acetyl chloride
  • 2-Methyl-2,4-butanediol
  • 3-Methyl-2-butenylphenyl ether
  • 3,3-Dimethylallyl bromide
  • 1c-chloro-3-methyl-but-1-ene

DownStream

  • 4,5-Dihydro-2-[(3-methyl-2-buten-1-yl)thio]thiazole
  • 3,6-dimethyl-2-methylidene-N,N-di(propan-2-yl)hept-5-enamide
  • (E)-2-ethylidene-N,N-diisopropyl-6-methylhept-5-enamide
  • 2,3-dibromo-1-chloro-3-methylbutane
  • N-(3-methylbut-2-enyl)-N-phenylacetamide
  • 2-Heptene, 2-methyl-
  • 3,3-DIMETHYL-1-HEXENE
  • 5-methylhex-4-en-1-ol
  • 2,2-Dimethylbutanoic acid
  • 4-methylpent-3-enoic acid

Customs

[ HS Code ]: 2903299090

[ Summary ]:
2903299090 other unsaturated chlorinated derivatives of acyclic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

Articles

Allylic Rearrangement in the Reactions of 1-Chloro-3-methyl-2-butene; an Attempt at Total Synthesis of Geraniol. Kwart H and Miller RK.

J. Am. Chem. Soc. 76(21) , 5403-5, (1954)

The influence of orbital asymmetry on the kinetics of the gas-phase reactions of ozone with unsaturated compounds. Johnson D, et al.

Phys. Chem. Chem. Phys. 2(3) , 323-28, (2000)

Allylic Chlorides. VIII. 1-Chloro-3-methyl-2-butene. Hatch LF and Gerhardt LS.

J. Am. Chem. Soc. 71(5) , 1679-80, (1949)


More Articles

Related Compounds

  • 1-chloro-3-methyl-2(Z),6(Z)-octadien-4-yne
  • 1-chloro-3-methyl-2,6-diphenylpiperidin-4-one
  • 1-chloro-3-methyl-2-phospholene 1-oxide
  • 1-chloro-3-methyl-2-phenylmethoxybenzene
  • 1-chloro-3-methyl-2,5-dihydro-1λ5-phosphole 1-oxide
  • 1-chloro-3-methyl-2,5-dihydrophosphole
  • 4-cyclopropaneamido-N-[(4-fluorophenyl)methyl]-3-(pyridin-2-yl)-1,2-thiazole-5-carboxamide
  • N~2~-benzyl-5-[(3-chloro-4-methoxyphenyl)sulfonyl]-N~2~-methylpyrimidine-2,4-diamine
  • N2-benzyl-5-((3-chloro-4-methoxyphenyl)sulfonyl)-N2-ethylpyrimidine-2,4-diamine
  • 5-((3-chloro-4-methoxyphenyl)sulfonyl)-2-(3,4-dihydroisoquinolin-2(1H)-yl)pyrimidin-4-amine
  • 5-((3-Chloro-4-methoxyphenyl)sulfonyl)-2-thiomorpholinopyrimidin-4-amine
  • Ethyl 1-[4-amino-5-(4-ethylbenzenesulfonyl)pyrimidin-2-yl]piperidine-4-carboxylate
  • Tert-butyl (1-(4-amino-5-((4-ethylphenyl)sulfonyl)pyrimidin-2-yl)piperidin-4-yl)carbamate
  • N-(2-methoxybenzyl)indolizine-2-carboxamide
  • 2-[4-(2-Chlorophenyl)piperazin-1-yl]-5-(4-ethylbenzenesulfonyl)pyrimidin-4-amine
  • 2-[4-(5-Chloro-2-methylphenyl)piperazin-1-yl]-5-(4-ethylbenzenesulfonyl)pyrimidin-4-amine
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