1-Chloro-3-methyl-2-butene

Suppliers

Names

[ CAS No. ]:
503-60-6

[ Name ]:
1-Chloro-3-methyl-2-butene

[Synonym ]:
1-chloro-3-methylbut-2-ene
Prenyl Chloride
1-Chloro-3-methyl-2-butene
EINECS 207-972-7
MFCD00000982
2-Butene, 1-chloro-3-methyl-

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
109.0±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C₅H₉Cl

[ Molecular Weight ]:
104.578

[ Flash Point ]:
13.3±0.0 °C

[ Exact Mass ]:
104.039276

[ LogP ]:
2.72

[ Vapour Pressure ]:
29.6±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.431

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H315-H319-H335

[ Precautionary Statements ]:
P210-P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F:Flammable;Xi:Irritant;

[ Risk Phrases ]:
R11;R36/37/38

[ Safety Phrases ]:
S16-S26-S27-S36/37/39

[ RIDADR ]:
UN 1993 3/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3

[ HS Code ]:
2903299090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

3-Methyl-2-buten-1-ol
2-Methyl-3-buten-2-ol
isoprene
(E)-oct-4-en-3-one
3-CHLORO-3-METHYL-1-BUTENE
Acetyl chloride
2-Methyl-2,4-butanediol
3-Methyl-2-butenylphenyl ether
3,3-Dimethylallyl bromide
1c-chloro-3-methyl-but-1-ene

DownStream

4,5-Dihydro-2-[(3-methyl-2-buten-1-yl)thio]thiazole
3,6-dimethyl-2-methylidene-N,N-di(propan-2-yl)hept-5-enamide
(E)-2-ethylidene-N,N-diisopropyl-6-methylhept-5-enamide
2,3-dibromo-1-chloro-3-methylbutane
N-(3-methylbut-2-enyl)-N-phenylacetamide
2-Heptene, 2-methyl-
3,3-DIMETHYL-1-HEXENE
5-methylhex-4-en-1-ol
2,2-Dimethylbutanoic acid
4-methylpent-3-enoic acid

Customs

[ HS Code ]: 2903299090

[ Summary ]:
2903299090 other unsaturated chlorinated derivatives of acyclic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

Articles

Allylic Rearrangement in the Reactions of 1-Chloro-3-methyl-2-butene; an Attempt at Total Synthesis of Geraniol. Kwart H and Miller RK.

J. Am. Chem. Soc. 76(21) , 5403-5, (1954)

The influence of orbital asymmetry on the kinetics of the gas-phase reactions of ozone with unsaturated compounds. Johnson D, et al.

Phys. Chem. Chem. Phys. 2(3) , 323-28, (2000)

Allylic Chlorides. VIII. 1-Chloro-3-methyl-2-butene. Hatch LF and Gerhardt LS.

J. Am. Chem. Soc. 71(5) , 1679-80, (1949)

1-chloro-3-methyl-2(Z),6(Z)-octadien-4-yne
1-chloro-3-methyl-2,6-diphenylpiperidin-4-one
1-chloro-3-methyl-2-phospholene 1-oxide
1-chloro-3-methyl-2-phenylmethoxybenzene
1-chloro-3-methyl-2,5-dihydro-1λ5-phosphole 1-oxide
1-chloro-3-methyl-2,5-dihydrophosphole
6-Fluoropyridazine-4-carboxylic acid
(5H-Pyrrolo[2,3-b]pyrazin-6-yl)methanamine
2-[(3,5-Dimethylpiperidin-1-yl)methyl]-1,3-thiazole-4-carboxylic acid
2-[(3-Methylpiperidin-1-yl)methyl]-1,3-thiazole-4-carboxylic acid
4-Chloro-3,5-difluorobenzyl chloride
3-{[(4-Chlorophenyl)methyl]sulfanyl}propanal
Methyl 2-oxo-2-(triethylsilyl)acetate
2-Iodo-4-(trifluoromethoxy)benzoic acid
4-Chloro-2-cyclopropanecarbonyl-5-fluorophenol
1-(5-Chloro-4-fluoro-2-hydroxyphenyl)propan-1-one

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