5-Hexenyl Acetate

Names

[ CAS No. ]:
5048-26-0

[ Name ]:
5-Hexenyl Acetate

[Synonym ]:
MFCD00060856
hex-5-enyl acetate
Acetic Acid 5-Hexenyl Ester
5-Hexenyl acetate
6-Acetoxy-1-hexene

Chemical & Physical Properties

[ Density]:
0.883 g/mL at 25ºC(lit.)

[ Boiling Point ]:
173-174ºC(lit.)

[ Molecular Formula ]:
C₈H₁₄O₂

[ Molecular Weight ]:
142.19600

[ Flash Point ]:
141 °F

[ Exact Mass ]:
142.09900

[ PSA ]:
26.30000

[ LogP ]:
1.90580

[ Index of Refraction ]:
n20/D 1.423(lit.)

MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ Risk Phrases ]:
10

[ Safety Phrases ]:
16

[ RIDADR ]:
UN 3272 3/PG 3

[ HS Code ]:
2915390090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

1-Hexen-6-ol
Ethanoic anhydride
Acetyl chloride
ethyl acetate
hex-5-enyl hydroperoxide
lead tetraacetate
UNII:JR71SUM5E9
hex-5-en-1-ol,methanesulfonic acid
acetic acid
1,5-Hexadiene

DownStream

1,3-Dioxolane-4-butanol,2,2-dimethyl-, 4-acetate
5-oxopentyl acetate
Hexan-1,6-diol
acetic acid,hexadec-7-yn-1-ol
(6-methyl-7-oxohept-5-enyl) acetate
1-Hexen-6-ol
1,5-Pentanediol
7-oxohept-5-enyl acetate
(E)-5-(2-CARBOXYVINYL)URIDINE
Hexyl acetate

Customs

[ HS Code ]: 2915390090

[ Summary ]:
2915390090. esters of acetic acid. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:5.5%. General tariff:30.0%

Articles

Synthesis of tri-substituted vinyl boronates via ruthenium-catalyzed olefin cross-metathesis Morrill C, et al.

Tetrahedron Lett. 45.41 , 7733-7736, (2004)

Nonconjugated dienes from 1-alkenes: Application to the synthesis of sex pheromone (4E, 7Z)-4, 7-Tridecadienyl acetate Kim TH and Park KM

Tetrahedron Lett. 36.27 , 4833-4836, (1995)

Ring-opening metathesis polymerization of vinylnorbornene and following polymer modifications Balcar H, et al.

J. Polymer Res. 21.9 , 1-8.