Cyanogen bromide

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Names

[ CAS No. ]:
506-68-3

[ Name ]:
Cyanogen bromide

[Synonym ]:
carbononitridic bromide
Cyanogen bromide
bromure cyanic
Bromocyanide
Cyanicbromid
EINECS 208-051-2
Cyanic bromide
MFCD00011597

Chemical & Physical Properties

[ Density]:
2.1±0.1 g/cm3

[ Boiling Point ]:
61.5±9.0 °C at 760 mmHg

[ Melting Point ]:
50-53 °C(lit.)

[ Molecular Formula ]:
CBrN

[ Molecular Weight ]:
105.921

[ Flash Point ]:
-9.0±18.7 °C

[ Exact Mass ]:
104.921402

[ PSA ]:
23.79000

[ LogP ]:
0.85

[ Vapour density ]:
3.65 (vs air)

[ Vapour Pressure ]:
184.9±0.1 mmHg at 25°C

[ Index of Refraction ]:
1.467

[ Stability ]:
Stable. Reacts violently with water and with mineral and organic acids.

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
GT2100000
CHEMICAL NAME :
Cyanogen bromide
CAS REGISTRY NUMBER :
506-68-3
BEILSTEIN REFERENCE NO. :
1697296
LAST UPDATED :
199710
DATA ITEMS CITED :
7
MOLECULAR FORMULA :
C-Br-N
MOLECULAR WEIGHT :
105.93
WISWESSER LINE NOTATION :
E CN

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Human
DOSE/DURATION :
92 ppm/10M
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: PB214-270
TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
500 mg/m3/10M
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NDRC** National Defense Research Committee, Office of Scientific Research and Development, Progress Report. Volume(issue)/page/year: No.9-4-1-9,1943 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 84594 No. of Facilities: 231 (estimated) No. of Industries: 4 No. of Occupations: 4 No. of Employees: 2222 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 84594 No. of Facilities: 54 (estimated) No. of Industries: 3 No. of Occupations: 5 No. of Employees: 2172 (estimated) No. of Female Employees: 605 (estimated)

Safety Information

[ Symbol ]:

GHS05, GHS06, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H300 + H310 + H330-H314-H410

[ Supplemental HS ]:
Contact with acids liberates very toxic gas.

[ Precautionary Statements ]:
P260-P264-P273-P280-P284-P301 + P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
T+:Verytoxic;N:Dangerous for the environment;

[ Risk Phrases ]:
R26/27/28;R34;R40;R50/53

[ Safety Phrases ]:
S53-S28-S36/37/39-S45-S60-S61-S26-S16

[ RIDADR ]:
UN 3390 6.1/PG 1

[ WGK Germany ]:
3

[ RTECS ]:
GT2100000

[ Packaging Group ]:
I

[ Hazard Class ]:
6.1

[ HS Code ]:
2853009021

Synthetic Route

Precursor & DownStream

Precursor

  • Sodium cyanide
  • HYDROGEN CYANIDE
  • Hydrogen bromide
  • Bromine
  • sodium cyanide
  • 2H-1,2-oxazine
  • Water
  • Potassium thiocyanate
  • Sodium N-bromo-p-toluenesulphonamidate

DownStream

  • Thioperoxydicarbonicdiamide ([(H2N)C(S)]2S2), N,N'-dimethyl-N,N'-diphenyl-
  • Ethyl 2-amino-3-methyl-3H-imidazo[4,5-b]pyridine-6-carboxylate
  • 1,1-Di(1H-imidazol-1-yl)methanimine
  • (4-methylphenyl)cyanamide
  • (E,E)-3,7,11-trimethyl-2,6,10-dodecatrienyl bromide
  • 3-bromocarbonylamino-2-methyl-1H-quinoline-4-one
  • Aurachin D
  • aurachin E
  • [(2R,3S,5R)-2-(hydroxymethyl)-5-(5-methyl-2,4-dioxopyrimidin-1-yl)oxolan-3-yl] thiocyanate
  • 5-IODO-1H-BENZIMIDAZOLE-2-AMINE

Customs

[ HS Code ]: 2853009021

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