5-Amino-2-methylbenzonitrile

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Names

[ CAS No. ]:
50670-64-9

[ Name ]:
5-Amino-2-methylbenzonitrile

[Synonym ]:
5-Amino-2-methylbenzonitrile
MFCD00017608
Benzonitrile, 5-amino-2-methyl-

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
300.3±22.0 °C at 760 mmHg

[ Melting Point ]:
88-91ºC(lit.)

[ Molecular Formula ]:
C₈H₈N₂

[ Molecular Weight ]:
132.163

[ Flash Point ]:
135.4±22.3 °C

[ Exact Mass ]:
132.068741

[ PSA ]:
49.81000

[ LogP ]:
1.53

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.576

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi,T

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Precursor & DownStream

Precursor

2-Methyl-5-nitrobenzonitrile
3-Bromo-4-methylaniline
o-Tolunitrile

DownStream

5-Bromo-2-methylbenzoic acid
4-Bromo-2-cyanobenzaldehyde
5-Amino-2-methylbenzoic acid
5-Bromo-2-methylbenzonitrile
4-Bromo-2-cyanobenzyl bromide
1-(5-bromo-2-methylphenyl)ethanone
1-(5-iodo-2-methylphenyl)ethanone
5-iodo-2-methylbenzenecarbonitrile

Articles

Reaction of benzal bromides in water/dioxane system for easy access to benzaldehydes and 2-formylbenzonitriles (2-cyanobenzaldehydes). Di Mola A, et al.

ARKIVOC 4 , 10-21, (2016)

5-Amino-2-methoxy-4-methylbenzonitrile
5-Amino-2-bromo-4-methylbenzonitrile
5-amino-2-fluoro-4-methylbenzonitrile
5-Amino-2-chloro-4-methylbenzonitrile
5-Amino-4-fluoro-2-methylbenzonitrile
5-Amino-4-chloro-2-methylbenzonitrile
2-(2-Hydroxyethyl)-2,3,5,6,7,8-hexahydrocinnolin-3-one
2-[(2,4-Dimethyl-1,3-thiazol-5-yl)methyl]-2,3,5,6,7,8-hexahydrocinnolin-3-one
2-(2-Methylprop-2-en-1-yl)-2,3,5,6,7,8-hexahydrocinnolin-3-one
6-Methyl-2-[2-(piperidin-1-yl)ethyl]-2,3,5,6,7,8-hexahydrocinnolin-3-one
6-methyl-2-[2-(1H-pyrazol-1-yl)ethyl]-2,3,5,6,7,8-hexahydrocinnolin-3-one
2-[2-(pyrrolidin-1-yl)ethyl]-2H,3H,5H,7H,8H-pyrano[4,3-c]pyridazin-3-one
2-(but-2-yn-1-yl)-2H,3H,5H,7H,8H-pyrano[4,3-c]pyridazin-3-one
2-(2,2,2-trifluoroethyl)-2H,3H,5H,7H,8H-pyrano[4,3-c]pyridazin-3-one
3-(Azetidin-3-yl)-3,4-dihydropyrimidin-4-one
3-(But-2-yn-1-yl)-6-methyl-3,4-dihydropyrimidin-4-one

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