2-Diphenylphosphinobenzaldehyde

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Names

[ CAS No. ]:
50777-76-9

[ Name ]:
2-Diphenylphosphinobenzaldehyde

[Synonym ]:
Benzaldehyde, 2-(diphenylphosphino)-
2-Diphenylphosphinobenzaldehyde
2-diphenylphosphanylbenzaldehyde
(2-Formylphenyl)diphenylphosphine
MFCD00013367
(2-Formylphenyl)diphenylphosphine o-(Diphenylphosphino)benzaldehyde
o-(diphenylphosphino)benzaldehyde
2-(Diphenylphosphino)benzaldehyde
2-Diphenylphosphino benzaldehyde

Chemical & Physical Properties

[ Boiling Point ]:
417.4±28.0 °C at 760 mmHg

[ Melting Point ]:
112-115 °C(lit.)

[ Molecular Formula ]:
C19H15OP

[ Molecular Weight ]:
290.296

[ Flash Point ]:
206.3±24.0 °C

[ Exact Mass ]:
290.086060

[ PSA ]:
30.66000

[ LogP ]:
5.11

[ Vapour Pressure ]:
0.0±1.0 mmHg at 25°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2912299000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2-diphenylphosphanyl-N,N-diethylbenzamide
  • N,N-Dimethylformamide
  • (2-Bromophenyl)(diphenyl)phosphine
  • 2-Bromobenzaldehyde
  • Diphenylphosphine
  • 2-(diphenylphosphinoyl)benzaldehyde
  • 2-(diphenylphosphinoyl)benzaldehyde
  • N,N-DIETHYLBENZAMIDE
  • Chlorodiphenylphosphine
  • 2-(2-Bromophenyl)-1,3-dioxolane

DownStream

  • sodium,(2S)-2-[(2-diphenylphosphanylphenyl)methylideneamino]-3,3-dimethylbutanoate
  • 1-(2-diphenylphosphanylphenyl)-N-ethylmethanimine
  • 1-(2-diphenylphosphanylphenyl)-N-(2-phenylethyl)methanimine
  • N-[2-(Diphenylphosphino)benzylidene]cyclohexylamine
  • 1-(2-diphenylphosphanylphenyl)-N-methylmethanimine
  • (1R,2R)-N1,N2-BIS(2-(DIPHENYLPHOSPHINO)BENZYL)CYCLOHEXANE-1,2-DIAMINE
  • platinum,triphenylphosphane
  • 1-(2-diphenylphosphanylphenyl)-N-phenylmethanimine

Customs

[ HS Code ]: 2912299000

[ Summary ]:
2912299000. other cyclic aldehydes without other oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

Investigation of antitumor potential of Ni(II) complexes with tridentate PNO acylhydrazones of 2-(diphenylphosphino)benzaldehyde and monodentate pseudohalides.

J. Biol. Inorg. Chem. 21 , 145-62, (2016)

Square-planar azido Ni(II) complex with condensation product of 2-(diphenylphosphino)benzaldehyde and Girard's T reagent was synthesized and its crystal structure was determined. Cytotoxic activity of...


More Articles

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