5-Bromo-2-fluorotoluene

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Names

[ CAS No. ]:
51437-00-4

[ Name ]:
5-Bromo-2-fluorotoluene

[Synonym ]:
4-Bromo-1-fluoro-2-methylbenzene
4-fluoro-3-methyl-1-bromo-benzene
Benzene,4-bromo-1-fluoro-2-methyl
1-bromo-4-fluoro-3-methylbenzene
5-Bromo-2-fluorotoluene
FR DE B1
5-BROMO-2-FLUORTOLUENE
5-Bromo-2-flurotoluene
2-FLUORO-5-BROMOTOLUENE
MFCD00000343
Benzene, 4-bromo-1-fluoro-2-methyl-
4-bromo-1-fluoro-2-methyl-benzene
EINECS 257-202-9

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
180.8±20.0 °C at 760 mmHg

[ Molecular Formula ]:
C7H6BrF

[ Molecular Weight ]:
189.025

[ Flash Point ]:
73.9±0.0 °C

[ Exact Mass ]:
187.963684

[ LogP ]:
3.44

[ Vapour Pressure ]:
1.2±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.527

[ Water Solubility ]:
INSOLUBLE

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
29036990

Synthetic Route

Precursor & DownStream

Precursor

  • 5-Bromo-2-fluorobenzaldehyde

DownStream

  • 4-(4-fluoro-3-methylphenyl)-4-oxobutanoic acid
  • (5-Bromo-2-fluorophenyl)methanol
  • 2-Fluoro-5-bromobenzylbromide
  • 4-Fluoro-3-methylbenzaldehyde
  • 3-Methyl-4-fluorophenylboronic acid
  • 4-Fluoro-3-methylbenzonitrile
  • 5-Bromo-2-fluoro-3-methylbenzaldehyde

Customs

[ HS Code ]: 2903999090

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Facilitated catecholamine transport through bulk and polymer-supported liquid membranes. Paugam M-F, et al.

J. Am. Chem. Soc. 118(41) , 9820-25, (1996)

Synthesis of 3-arylpropylamine derivatives from aryl halides using Heck reaction. Baek GH, et al.

Bull. Korean Chem. Soc. 20(2) , 233, (1999)


More Articles


Related Compounds

  • 5-bromo-4-chloro-2-fluorotoluene
  • 5-bromo-2-cyclopropyl-4-methoxy-6-(2-methylpropyl)pyrimidine
  • (5-bromo-2-hydroxy-3-methoxyphenyl)methyl-(2-methyl-1-phenylpropan-2-yl)azanium,chloride
  • 5-bromo-2-ethylbenzaldehyde
  • 5-bromo-2-pyridin-4-yl-1,3-benzoxazole
  • (5-bromo-2-hydroxy-3-methoxyphenyl)methyl-(2-phenylethyl)azanium,chloride
  • Methyl 5-hydroxyisoxazole-3-carboxylate
  • tert-Butyl 2-cyanobenzyl(methyl)carbamate
  • 7,9-Dibromo-9aH-pyrazino[1,2-a][1,3,5]triazine
  • Benzene, 1-(2-nitroethenyl)-3-propoxy-
  • 1-(Benzo[d][1,3]dioxol-5-yl)-3-(4-(dimethylamino)-2-morpholinopyrimidin-5-yl)urea
  • 2-(3,5-Dichlorophenyl)-1-methyl-5-(2-nitroethenyl)-1H-pyrrole
  • N-(2-(5-cyclopropyl-3-(trifluoromethyl)-1H-pyrazol-1-yl)ethyl)isonicotinamide
  • N-{2-[5-cyclopropyl-3-(trifluoromethyl)-1H-pyrazol-1-yl]ethyl}thiophene-2-carboxamide
  • 4-Methyl-N-[(1S,2S)-2-nitro-1-phenylpropyl]benzene-1-sulfonamide
  • 3-cyano-N-(2-(5-cyclopropyl-3-(trifluoromethyl)-1H-pyrazol-1-yl)ethyl)benzamide
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