DIETHYL (2-METHYLALLYL)PHOSPHONATE

Names

[ CAS No. ]:
51533-70-1

[ Name ]:
DIETHYL (2-METHYLALLYL)PHOSPHONATE

[Synonym ]:
MFCD05664300

Chemical & Physical Properties

[ Density]:
1.013 g/mL at 25ºC(lit.)

[ Boiling Point ]:
62ºC0.1 mm Hg(lit.)

[ Molecular Formula ]:
C₈H₁₇O₃P

[ Molecular Weight ]:
192.19300

[ Flash Point ]:
>230 °F

[ Exact Mass ]:
192.09200

[ PSA ]:
45.34000

[ LogP ]:
2.82860

[ Index of Refraction ]:
n20/D 1.4380(lit.)

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H319

[ Precautionary Statements ]:
P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
36

[ Safety Phrases ]:
26

[ RIDADR ]:
NONH for all modes of transport

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

2-Methyl-2-propen-1-yl acetate
Triethyl phosphite
3-Chloro-2-methyl-1-propene
3-Bromo-2-methylpropene

DownStream

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Gas-phase synchrotron FTIR spectroscopy of weakly volatile alkyl phosphonate and alkyl phosphate compounds: vibrational and conformational analysis in the terahertz/far-IR spectral domain.

J. Phys. Chem. B 114(50) , 16936-47, (2010)

The high brilliance of the AILES beamline at the SOLEIL synchrotron facility has been exploited for the study of the gas-phase vibrational spectra of weakly volatile organophosphorous compounds. The p...

Carbodiimides-key mediators in the synthesis of novel cytotoxic and analgesic/antiinflammatory motifs based on a-amino-, enaminophosphonates, and azaphosphones. Abdou WM, et al.

RSC Advances 3(5) , 1528-40, (2013)

diethyl (2-propionylaminoethyl)phosphonate
Diethyl(2-aminoethyl)phosphonatehydrochloride
diethyl (2-chloroethyl)phosphonate
diethyl (2-methoxyphenyl)phosphonate
diethyl (2-phenylcyclopropyl)phosphonate
Diethyl (2-methylphenyl)phosphonate
(4-(2-Fluorophenyl)thiophen-2-yl)methanamine
2,6-Difluoro-4-(methyl)thiophenol
(3S,11aR)-6-(benzyloxy)-N-(2,4-difluorobenzyl)-3-methyl-5,7-dioxo-2,3,5,7,11,11a-hexahydrooxazolo[3,2-a]pyrido[1,2-d]pyrazine-8-carboxamide
Phenylmethyl (2r)-2-(2-aminoethyl)-1-piperidinecarboxylate
1,2-Hydrazinedicarboximidamide, N-(2-methylphenyl)-
1-Cyclopentylhexan-3-one
Methyl 3-amino-4-({[tert-butyl(dimethyl)silyl]oxy}methyl)benzoate
1-Piperidineacetamide,4-[(4-fluorophenyl)methyl]-n-(3-nitrophenyl)-
N-(2,3-Dihydro-2-oxo-1H-indol-5-yl)-4-[(4-methoxyphenyl)methyl]-I+/--oxo-1-piperidineacetamide
1-Piperidineacetamide,4-[(4-fluorophenyl)methyl]-n-(4-nitrophenyl)-

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