DIETHYL (2-METHYLALLYL)PHOSPHONATE

Names

[ CAS No. ]:
51533-70-1

[ Name ]:
DIETHYL (2-METHYLALLYL)PHOSPHONATE

[Synonym ]:
MFCD05664300

Chemical & Physical Properties

[ Density]:
1.013 g/mL at 25ºC(lit.)

[ Boiling Point ]:
62ºC0.1 mm Hg(lit.)

[ Molecular Formula ]:
C₈H₁₇O₃P

[ Molecular Weight ]:
192.19300

[ Flash Point ]:
>230 °F

[ Exact Mass ]:
192.09200

[ PSA ]:
45.34000

[ LogP ]:
2.82860

[ Index of Refraction ]:
n20/D 1.4380(lit.)

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H319

[ Precautionary Statements ]:
P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
36

[ Safety Phrases ]:
26

[ RIDADR ]:
NONH for all modes of transport

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

2-Methyl-2-propen-1-yl acetate
Triethyl phosphite
3-Chloro-2-methyl-1-propene
3-Bromo-2-methylpropene

DownStream

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Gas-phase synchrotron FTIR spectroscopy of weakly volatile alkyl phosphonate and alkyl phosphate compounds: vibrational and conformational analysis in the terahertz/far-IR spectral domain.

J. Phys. Chem. B 114(50) , 16936-47, (2010)

The high brilliance of the AILES beamline at the SOLEIL synchrotron facility has been exploited for the study of the gas-phase vibrational spectra of weakly volatile organophosphorous compounds. The p...

Carbodiimides-key mediators in the synthesis of novel cytotoxic and analgesic/antiinflammatory motifs based on a-amino-, enaminophosphonates, and azaphosphones. Abdou WM, et al.

RSC Advances 3(5) , 1528-40, (2013)

diethyl (2-propionylaminoethyl)phosphonate
Diethyl(2-aminoethyl)phosphonatehydrochloride
diethyl (2-chloroethyl)phosphonate
diethyl (2-methoxyphenyl)phosphonate
diethyl (2-phenylcyclopropyl)phosphonate
Diethyl (2-methylphenyl)phosphonate
N-[cyano(cyclopropyl)methyl]-1-(2-fluorophenyl)-1H,4H,5H,6H-cyclopenta[c]pyrazole-3-carboxamide
N-(1-cyanocyclohexyl)-2-{[3-(2-hydroxyacetamido)phenyl]amino}propanamide
5-(2-Trimethylsilylethynyl)pyrimidin-4-amine
ethyl 3-[({4-[(4-methoxyphenyl)carbamoyl]-5-methyl-1H-1,2,3-triazol-1-yl}acetyl)amino]benzoate
Methyl 3-[(2,4-difluorophenoxy)methyl]benzoate
3-[(1E)-2-phenylethenyl]-1H-pyrazole-4-carbaldehyde
2-Amino-2-methylcyclohexane-1-carboxylic acid hydrochloride
1-(5-(furan-2-yl)isoxazol-3-yl)-N-(4-sulfamoylphenyl)cyclopropanecarboxamide
(1-Phenyl-1H-pyrazol-3-yl)methyl 2H-chromene-3-carboxylate
2-amino-6-chloro-4-(3-methoxyphenyl)-4H-benzo[h]chromene-3-carbonitrile

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