(2-Iodophenyl)methanol

Names

[ Name ]:
(2-Iodophenyl)methanol

[Synonym ]:
o-iodobenzyl alcohol
EINECS 225-933-2
2-iodobenzyl alcohol
Q1R BI
(2-Iodophenyl)methanol
Benzenemethanol, 2-iodo-
Benzyl alcohol, o-iodo-
MFCD00004610

Chemical & Physical Properties

[ Density]:
1.9±0.1 g/cm3

[ Boiling Point ]:
288.3±15.0 °C at 760 mmHg

[ Melting Point ]:
89-92 °C(lit.)

[ Molecular Formula ]:
C₇H₇IO

[ Molecular Weight ]:
234.03

[ Flash Point ]:
128.2±20.4 °C

[ Exact Mass ]:
233.954147

[ PSA ]:
20.23000

[ LogP ]:
2.07

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.648

[ Storage condition ]:
Store under Nitrogen

MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/38

[ Safety Phrases ]:
S22-S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2906299090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

2-Iodobenzoic acid
2-Iodobenzaldehyde
Benzyl alcohol
2-Iodobenzoyl chloride
2-(2-iodophenyl)acetyl chloride
2-Iodophenylacetic acid
methyl 2-(2-iodophenyl)acetate
Anthranilic acid

DownStream

2-Hex-1-ynyl-benzaldehyde
(2-Ethynylphenyl)methanol
1-iodo-2-pentylbenzene
2-Iodobenzylamine
(2-Iodophenyl)acetonitrile
α-Bromo-2-iodotoluene
1H-Inden-1-one,2,3-diphenyl-
Butylbenzene
Phthalide
2-(2-Iodophenyl)ethan-1-ol

Customs

[ HS Code ]: 2906299090

[ Summary ]:
2906299090 other aromatic alcohols。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

Articles

Synthesis of seven-membered lactones via nickel- and zinc-catalyzed highly regio- and stereoselective cyclization of 2-iodobenzyl alcohols with propiolates.

J. Am. Chem. Soc. 124(20) , 5630-1, (2002)

A new class of substituted seven-membered lactones 3 were conveniently synthesized via cyclization of o-iodobenzyl alcohol 1 (o-IC(6)H(4)CH(2)OH) with various propiolates 2 (RC triple bond CCOOMe) in ...

Synthesis of indenones via palladium-catalyzed annulation of internal alkynes. Larock RC, et al.

J. Org. Chem. 58(17) , 4579-83, (1993)

acetic acid,(2-iodophenyl)methanol
(4-Fluoro-2-iodophenyl)methanol
(5-(benzyloxy)-2-iodophenyl)methanol
(4-Amino-2-iodophenyl)methanol
(5-chloro-2-iodophenyl)methanol
(4-chloro-2-iodophenyl)methanol
(3-Chlorobicyclo[1.1.1]pentan-1-yl)pentafluoro-l6-sulfane
2-(But-3-en-1-yloxy)-6-chloro-3-propylquinazolin-4(3H)-one
Methyl 5-chloro-6-methoxy-2-methyl-1H-indole-3-carboxylate
Methyl 3-(2-methyl-1-oxo-1,2-dihydroisoquinolin-7-yl)propanoate
(3-(Methoxymethyl)-1-methyl-1H-pyrazol-5-yl)boronic acid
6-Bromo-1-(tetrahydrofuran-3-yl)-1H-pyrazolo[3,4-b]pyridine
6-Iodo-1,2,3-trimethyl-1H-indole
B-(3-chloro-4-formyl-2-pyridinyl)boronic acid
Methyl 2-methyl-7H-thieno[2',3':4,5]pyrrolo[3,2-d]thiazole-5-carboxylate
(3-Isopropoxypyrazin-2-yl)methanol

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