methyl ethyl acetoacetate

Names

[ CAS No. ]:
51756-08-2

[ Name ]:
methyl ethyl acetoacetate

[Synonym ]:
Methyl 2-ethylacetoacetate
methyl 2-ethyl-3-oxobutanoate
MFCD01632136
EINECS 257-381-3

Chemical & Physical Properties

[ Density]:
1.010 g/mL at 20 °C(lit.)

[ Boiling Point ]:
262.4ºC at 760mmHg

[ Molecular Formula ]:
C₇H₁₂O₃

[ Molecular Weight ]:
144.16800

[ Flash Point ]:
96.1ºC

[ Exact Mass ]:
144.07900

[ PSA ]:
43.37000

[ LogP ]:
0.77460

[ Index of Refraction ]:
n20/D 1.423

MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
23-24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2918300090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Bromoethane
Methyl acetoacetate
Ethyl iodide
Acetoacetic Acid
methyl acetoacetate sodium salt
Methanol
Sodium Methylate
Ethyl acetoacetate

DownStream

3-chloropentan-2-one
Salvadoricine

Customs

[ HS Code ]: 2918300090

[ Summary ]:
2918300090 other carboxylic acids with aldehyde or ketone function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles

Synthesis of multi ring-fused 2-pyridones via an acyl-ketene imine cyclocondensation.

Org. Lett. 8(5) , 935-8, (2006)

Polycyclic ring-fused 2-pyridones (5a-e and 9a-e) have been prepared via a microwave-assisted acyl-ketene imine cyclocondensation. Starting from 3,4-dihydroisoquinolines (4a-b) or 3,4-dihydroharman (8...

methyl ethyl cellulose
methyl ethyl(1,1,1,3,3,3-hexafluoroisopropyl)phosphonoacetate
methyl ethyl(2,2,2-trifluoroethyl)phosphonoacetate
1-methyl-2-[(1-oxoallyl)oxy]ethyl acetoacetate
Ethyl 2-acetyl-3-methylpentanoate
(1S)-2-ethoxy-1-methyl-2-oxoethyl 3-oxobutanoate
rac-(3R,5R)-3-amino-5-tert-butylpyrrolidin-2-one
rac-[(1R,2R)-2-(difluoromethyl)cyclopropyl]methanamine
1-(Chloromethyl)-3-(2-fluoroethyl)bicyclo[1.1.1]pentane
1-(Chloromethyl)-3-cyclobutylbicyclo[1.1.1]pentane
1-Butyl-3-(chloromethyl)bicyclo[1.1.1]pentane
1-(Chloromethyl)-3-(4-fluorophenyl)bicyclo[1.1.1]pentane
1-(Chloromethyl)-3-(2-fluorophenyl)bicyclo[1.1.1]pentane
1-(Chloromethyl)-3-[2-(2-methoxyethoxy)ethyl]bicyclo[1.1.1]pentane
1-(Chloromethyl)-3-(2,6-dimethylphenyl)bicyclo[1.1.1]pentane
1-(Chloromethyl)-3-(2,4-dimethylphenyl)bicyclo[1.1.1]pentane

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