Luminol

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Names

[ CAS No. ]:
521-31-3

[ Name ]:
Luminol

[Synonym ]:
EINECS 208-309-4
LUMINOL
5-Amino-2,3-dihydrophthalazine-1,4-dione
5-Amino-2,3-dihydro-1,4-phthalazinedione
Dia0003Luminol
o-Aminophthalhydride
LuminolFreeAcid
phthalazinedione
3-aminophthalic hydrazide
Diogenes Reagent
3-Aminophthaloylhydrazine
MFCD00006890
RARECHEM AH BS 0053

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
621.9ºC at 760 mmHg

[ Melting Point ]:
>300 °C(lit.)

[ Molecular Formula ]:
C8H7N3O2

[ Molecular Weight ]:
177.160

[ Flash Point ]:
329.9ºC

[ Exact Mass ]:
177.053833

[ PSA ]:
91.74000

[ LogP ]:
-0.71

[ Index of Refraction ]:
1.649

[ Stability ]:
Stable. Combustible. Incompatible with strong oxidizing agents, strong acids, strong bases, strong reducing agents. Emits light on reaction with oxidizers.

[ Water Solubility ]:
<0.1 g/100 mL at 19 ºC

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TH8890060
CHEMICAL NAME :
1,4-Phthalazinedione, 5-amino-2,3-dihydro-
CAS REGISTRY NUMBER :
521-31-3
LAST UPDATED :
199709
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C8-H7-N3-O2
MOLECULAR WEIGHT :
177.18

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD - Lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :
Sister chromatid exchange
TEST SYSTEM :
Rodent - hamster Lung
DOSE/DURATION :
500 umol/L
REFERENCE :
CHROAU Chromosoma. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 07094) V.1- 1939- Volume(issue)/page/year: 99,360,1990 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X7070 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 28 (estimated)

Safety Information

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R22;R36/37/38

[ Safety Phrases ]:
S26-S36/37-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
TH8890060

[ HS Code ]:
29339990

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 3-Nitrophthalhydrazide
  • 3-Aminophthalimide
  • 4-Amino-n-methylphthalimide
  • (2,3,3a,4,7,7a-Hexahydro-2-methyl-1,3-dioxo-1H-isoindol-4-yl)carbamic Acid Phenylmethyl Ester
  • 3-Nitrophthalic acid
  • 3-Nitrophthalimide
  • 2-Carboxy-3-ethyl nitrobenzoate
  • 2,4-diamino-isoindoline-1,3-dione
  • Water
  • Hydrazine hydrate

DownStream

  • 3-Aminophthalic acid
  • 3-Aminobenzoic acid
  • 5-(2-chloro-acetylamino)-2,3-dihydro-phthalazine-1,4-dione
  • Triethylammonium chloride
  • 1,4-Phthalazinedione,5-amino-

Customs

[ HS Code ]: 2933990090

[ Summary ]:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

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Related Compounds

  • Luminol
  • luminol-13c4
  • LUMINOLSODIUM
  • SODIUM LUMINOL
  • luminol radical
  • Luminol hydrochloride
  • 2-[1-(2,6-Dioxo-1,2,3,6-tetrahydropyrimidine-4-carbonyl)piperidin-2-yl]acetic acid
  • Benzoic acid, 4-fluoro-3-[[2-(3-thiomorpholinyl)acetyl]amino]-, methyl ester
  • 1-Pentyl-2-piperidineacetic acid
  • 6-(3-Aminopropyl)benzothiazole
  • 2-(2-Hydroxy-5-nitrophenyl)butanoic acid
  • Methyl 1-(4-bromo-2-fluorobenzoyl)-2-piperidineacetate
  • 2-(1-(Methylsulfonyl)piperidin-2-yl)acetic acid
  • 3-methyl-4-(prop-2-en-1-yl)-4,5-dihydro-1H-1,2,4-triazol-5-one
  • 3-(3-Bromo-5-fluorophenyl)-1,2,4-oxadiazol-5-amine
  • 2-(3-Bromo-5-fluorophenyl)-4-chloro-5-ethyl-6-methylpyrimidine
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