p-Chlorobenzotrichloride

Suppliers

Names

[ CAS No. ]:
5216-25-1

[ Name ]:
p-Chlorobenzotrichloride

[Synonym ]:
4-Chlorbenzotrichlorid
Tetrachlorotoluene
1-Chloro-4-(trichloromethyl)benzene
α,α,α-trichloro-4-chlorotoluene
p-chlorotrichloromethylbenzene
PCTC
P-CHLOROBENZOTRICHLORIDE
P-CHLORO BENOTRICHLORIDE
4-chloro-trichloromethylbenzene
Benzene, 1-chloro-4-(trichloromethyl)-
p-Chlorbenzotrichlorid
9-chloro-1,1,1-trichloromethylbenzene
4-Chlorobenzotrichlo
α,α,α,4-Tetrachlorotoluene
p-Chlorotrichlorotoluene
EINECS 226-009-1
Toluene, p,α,α,α-tetrachloro-
MFCD00000790
4-chlorobenzotrichlorid

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
245.0±0.0 °C at 760 mmHg

[ Melting Point ]:
5.8 °C

[ Molecular Formula ]:
C7H4Cl4

[ Molecular Weight ]:
229.919

[ Flash Point ]:
109.9±23.3 °C

[ Exact Mass ]:
227.906708

[ LogP ]:
3.94

[ Vapour Pressure ]:
0.0±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.571

[ Stability ]:
Stable. Combustible. Incompatible with strong oxidizing agents.

[ Water Solubility ]:
decomposes

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
XT8580000
CHEMICAL NAME :
Toluene, alpha,alpha,alpha,p-tetrachloro-
CAS REGISTRY NUMBER :
5216-25-1
BEILSTEIN REFERENCE NO. :
1866549
LAST UPDATED :
199710
DATA ITEMS CITED :
9
MOLECULAR FORMULA :
C7-H4-Cl4

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
820 mg/kg
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - chromodacryorrhea Behavioral - tremor Gastrointestinal - hypermotility, diarrhea
REFERENCE :
EPASR* United States Environmental Protection Agency, Office of Pesticides and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW, Washington, DC 20460) History unknown. Volume(issue)/page/year: 8EHQ-0281-0360
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
125 mg/m3
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold Lungs, Thorax, or Respiration - structural or functional change in trachea or bronchi
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 28(6),41,1984
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
700 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - changes in motor activity (specific assay)
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 28(6),41,1984
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
125 mg/m3
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold Lungs, Thorax, or Respiration - structural or functional change in trachea or bronchi
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 28(6),41,1984
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
EPASR* United States Environmental Protection Agency, Office of Pesticides and Toxic Substances. (U.S. Environmental Protection Agency, 401 M St., SW, Washington, DC 20460) History unknown. Volume(issue)/page/year: 8EHQ-0281-0360 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
9670 ug/m3/17W-I
TOXIC EFFECTS :
Blood - other changes Nutritional and Gross Metabolic - weight loss or decreased weight gain Related to Chronic Data - death
REFERENCE :
GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 28(6),41,1984
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
94500 ug/m3/6H/30D-I
TOXIC EFFECTS :
Blood - changes in erythrocyte (RBC) count Nutritional and Gross Metabolic - weight loss or decreased weight gain Related to Chronic Data - death
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0526145

Safety Information

[ Hazard Codes ]:
T:Toxic;

[ Risk Phrases ]:
R21/22;R37/38;R45;R48/23;R62

[ Safety Phrases ]:
S53-S45

[ RIDADR ]:
UN 1760 8/PG 2

[ WGK Germany ]:
3

[ RTECS ]:
XT8580000

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
2903999090

Synthetic Route

Precursor & DownStream

Precursor

  • 4-Chlorotoluene
  • 4-chloro-1-(dichloromethyl)benzene
  • Tosyl chloride
  • Benzotrichloride
  • 4-Hydroxybenzoic acid
  • antimony(v) chloride
  • molecular iodine
  • Benzyl chloride

DownStream

  • 3,4-Difluorobenzoic acid
  • 3-Bromo-4-chlorobenzotrifluoride
  • 3,4,5-trichlorobenzotrichloride
  • 1,2,3,4-tetrachloro-5-(trichloromethyl)benzene
  • 3,4-Dichlorobenzotrichloride
  • 2,4,5-trichloro-1-(trichloromethyl)benzene
  • Benzoic acid,4-chloro-, phenyl ester
  • 4,4'-Dichlorobenzophenone
  • 2,5-bis(4-chlorophenyl)-1,3,4-oxadiazole
  • 4-Chlorobenzotrifluoride

Customs

[ HS Code ]: 2903999090

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%


Related Compounds

  • p-(Decanoyloxy)benzenesulfonic acid sodium salt
  • p-Nitrophenyldithiocarbamic acid ethyl ester
  • p-Fluoro Fentanyl-d3
  • P-HEXYLOXYBENZYLIDENE P-BUTYLANILINE
  • p-Nitrophenyldithiocarbamic acid methyl ester
  • p-Chloro-N-[2,4-diamino-6-quinazolinyl]benzamide
  • 5-(Aminomethyl)-3-iodo-2,4-dimethylbenzene-1-thiol
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • 2-cyclopropyl-2-{2-[({[(9H-fluoren-9-yl)methoxy]carbonyl}amino)methyl]-3,3,3-trifluoropropanamido}acetic acid
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine