2-(methylthio)cyclohexanone

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Names

[ CAS No. ]:
52190-35-9

[ Name ]:
2-(methylthio)cyclohexanone

[Synonym ]:
2-methylsulfanyl-cyclohexanone
2-(Methylthio)cyclohexanone
MFCD00209603
2-methylthiocyclohexane
2-Methylmercapto-cyclohexanon

Chemical & Physical Properties

[ Density]:
1.069 g/mL at 25ºC(lit.)

[ Boiling Point ]:
45ºC10.1 mm Hg(lit.)

[ Molecular Formula ]:
C7H12OS

[ Molecular Weight ]:
144.23500

[ Flash Point ]:
193 °F

[ Exact Mass ]:
144.06100

[ PSA ]:
42.37000

[ LogP ]:
1.86110

[ Index of Refraction ]:
n20/D 1.508(lit.)

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
26-36

[ RIDADR ]:
NA 1993 / PGIII

[ WGK Germany ]:
3

[ HS Code ]:
2930909090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 1-(trimethylsilyloxy)-cyclohex-1-ene
  • Trimethyldisulfanium tetrafluoroborate
  • Cyclohexene
  • N-(2-(methylthio)cyclohexylidene)cyclohexanamine
  • Chlorocyclohexane
  • Sodium thiomethoxide
  • Dimethyl disulfide
  • Cyclohexanone
  • Dimethyl sulfoxide

DownStream

  • 2-Benzylidenecyclohexanone
  • 1,2-Cyclohexanedione
  • 2-METHYL-2-CYCLOHEXEN-1-ONE
  • 2-benzylcyclohex-2-en-1-one
  • 2-propylsulfonylcyclohexan-1-one
  • 2-hexylsulfonylcyclohexan-1-one
  • 2-(2-phenylethylsulfonyl)cyclohexan-1-one
  • 2-nonylsulfonylcyclohexan-1-one
  • 2-but-3-enylsulfonylcyclohexan-1-one
  • ethyl 3-(6-oxocyclohexen-1-yl)propanoate

Customs

[ HS Code ]: 2930909090

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Studies on the stereoselectivity of hydride reductions on 2-(methylthio)-and 2-(methylsulfonyl) cyclohexanones. Carmen CM, et al.

J. Org. Chem. 52(16) , 3619-3625, (1987)

Nitrone formation in phosphate buffer and aqueous solutions: novel chemistry inspired by a natural product. Pansanit A, et al.

Tetrahedron Lett. 53(16) , 2129-2131, (2012)

Axial/equatorial proportions for 2-substituted cyclohexanones. Basso EA, et al.

J. Org. Chem. 58(27) , 7865-7869, (1993)


More Articles

Related Compounds

  • 2-methyl-2-(methylthio)cyclohexanone
  • 2-benzyl-2-(methylthio)cyclohexanone
  • 4-(benzyloxy)-2-(methylthio)cyclohexanone
  • .cis-4-tert-butyl-2-(methylthio)cyclohexanone
  • 2-(METHYLTHIO)-4(5H)-THIAZOLONE
  • 2-(Methylthio)phenol
  • Pramipexole Impurity 49
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 1-Cyclohexene-1-carboxaldehyde, 4-ethenyl-
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • Succinic acid chlorocarbonyloxymethyl ester methyl ester
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • 1-(2-Methyl-2,3-dihydro-1-benzofuran-5-yl)cyclopropane-1-carbonitrile
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide