6-Bromo-2,3-dihydrobenzo[b][1,4]dioxine

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Names

[ Name ]:
6-Bromo-2,3-dihydrobenzo[b][1,4]dioxine

[Synonym ]:
EINECS 257-817-2
1,4-Benzodioxin, 6-bromo-2,3-dihydro-
6-Bromo-2,3-dihydro-1,4-benzodioxine
4-Bromo-1,2-ethylenedioxybenzene
6-Bromo-2,3-dihydrobenzo[b][1,4]dioxine
6-BroMo-1,4-benzodioxane
MFCD00040750

Chemical & Physical Properties

[ Density]:
1.6±0.1 g/cm3

[ Boiling Point ]:
258.3±39.0 °C at 760 mmHg

[ Molecular Formula ]:
C₈H₇BrO₂

[ Molecular Weight ]:
215.04

[ Flash Point ]:
117.6±22.6 °C

[ Exact Mass ]:
213.962936

[ PSA ]:
18.46000

[ LogP ]:
3.04

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.579

[ Storage condition ]:
Room temperature.

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36/37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2932999099

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

1-(2,3-dihydro-1,4-benzodioxin-6-yl)piperazine
2,3-Dihydro-1,4-benzodioxine-6-carboxylic acid
1,4-Benzodioxane-6-aldehyde
6-BROMO-7-NITRO-2,3-DIHYDROBENZO[B][1,4]DIOXINE
3-[3,4-(ETHYLENEDIOXY)PHENYL]-1-PROPENE
2,3-Dihydrobenzo[b][1,4]dioxin-6-ol
2,3-Dihydro-1,4-benzodioxin-6-ylacetic acid
1,4-Benzodioxan-6-amine
6-diphenylphosphoryl-2,3-dihydro-1,4-benzodioxine
6-diphenylphosphoryl-5-iodo-2,3-dihydro-1,4-benzodioxine

Customs

[ HS Code ]: 2932999099

[ Summary ]:
2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Chiral biphenyl diphosphines for asymmetric catalysis: Stereoelectronic design and industrial perspectives. Jeulin, Séverine, et al.

Proc. Natl. Acad. Sci. U. S. A. 101(16) , 5799-5804, (2004)

An Efficient Method for the Preparation of Tertiary Esters by Palladium-Catalyzed Alkoxycarbonylation of Aryl Bromides. Xin, Zhuo, et al.

Org. Lett. 14(1) , 284-287, (2011)

6-Bromo-2,3-dihydrobenzo[b][1,4]dioxine-5-carbaldehyde
(6-BROMO-2,3-DIHYDROBENZO[B][1,4]DIOXIN-2-YL)METHANOL
6-BROMO-7-NITRO-2,3-DIHYDROBENZO[B][1,4]DIOXINE
6-Bromo-7-fluoro-2,3-dihydro-1,4-benzodioxin
7-BROMO-2,3-DIHYDROBENZO[B][1,4]DIOXINE-5-CARBOXYLIC ACID
(R)-(6-BROMO-2,3-DIHYDROBENZO[B][1,4]DIOXIN-2-YL)METHANOL