2-Methylbenzamide

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Names

[ CAS No. ]:
527-85-5

[ Name ]:
2-Methylbenzamide

[Synonym ]:
o-Toluene amide
o-Toluic amide
o-tolylamide
Formyl-o-toluidine
2-Me-Ph-CO-NH2
2-TOLUAMIDE
2-methyl-benzamid
2-METHYLBENZAMIDE
o-Methylbenzamide

Chemical & Physical Properties

[ Density]:
1.086 g/cm3

[ Boiling Point ]:
254.3ºC at 760 mmHg

[ Melting Point ]:
141-142ºC(lit.)

[ Molecular Formula ]:
C8H9NO

[ Molecular Weight ]:
135.16300

[ Flash Point ]:
107.6ºC

[ Exact Mass ]:
135.06800

[ PSA ]:
43.09000

[ LogP ]:
1.79420

[ Index of Refraction ]:
1.556

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn

[ Safety Phrases ]:
S22-S24/25

[ RIDADR ]:
NONH for all modes of transport

[ HS Code ]:
2924299090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 4-Iodotoluene
  • carbon monoxide
  • o-Tolunitrile
  • 2-Bromotoluene
  • O-Toluoylchloride
  • 2-Methylbenzaldehyde
  • 2-Methylbenzyl Alcohol
  • 2-Methylacetophenone
  • Adenosine
  • 4-METHYL-N-(2-METHYL-BENZOYL)-BENZENESULFONAMIDE

DownStream

  • 2-methyl-benzenemethanaminhydrochloride
  • 2-Methylbenzyl Alcohol
  • o-Xylylamine
  • o-Toluidine
  • Ethyl 2-methylbenzoate
  • o-Tolunitrile
  • 1-Isocyanato-2-methylbenzene
  • 2-Methylbenzothioamide
  • 2-Methylcyclohexa-2,5-diene-1,4-dione

Customs

[ HS Code ]: 2924299090

[ Summary ]:
2924299090. other cyclic amides (including cyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

First total synthesis of the phenolic 7,8-dihydro-8-oxoprotoberberine alkaloid, cerasonine.

Chem. Pharm. Bull. 56(7) , 1026-9, (2008)

First total synthesis of the phenolic protoberberine, cerasonine, was accomplished through a coupling reaction between o-toluamide and benzonitrile. This key step provided the 3-arylisoquinoline which...


More Articles

Related Compounds

  • 3-Amino2-methylbenzamide
  • 5-Iodo-2-methylbenzamide
  • 3-Iodo-2-methylbenzamide
  • N-butyl-2-methylbenzamide
  • N-decyl-2-methylbenzamide
  • N-hexyl-2-methylbenzamide
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 6-Fluoro-3-[(methylsulfonyl)oxy]-2-pyrazinecarbonitrile
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide