8-METHYL-8-AZABICYCLO[3.2.1]OCTANE

Names

[ CAS No. ]:
529-17-9

[ Name ]:
8-METHYL-8-AZABICYCLO[3.2.1]OCTANE

[Synonym ]:
8-Azabicyclo[3.2.1]octane,8-methyl
endo-8-methyl-8-azabicyclo[3.2.1]octane
Tropane
8-methyl-8-aza-bicyclo[3.2.1]octane
8-METHYL-8-AZABICYCLO[3.2.1]OCTANE

Chemical & Physical Properties

[ Density]:
0.934g/cm3

[ Boiling Point ]:
166ºC at 760mmHg

[ Molecular Formula ]:
C₈H₁₅N

[ Molecular Weight ]:
125.21100

[ Flash Point ]:
42.2ºC

[ Exact Mass ]:
125.12000

[ PSA ]:
3.24000

[ LogP ]:
1.57100

[ Index of Refraction ]:
n20/D 1.477(lit.)

MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
10-36/37/38

[ Safety Phrases ]:
16-26-36

[ RIDADR ]:
UN 1993 3/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3.2

[ HS Code ]:
2933990090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Tropinone
carbon monoxide
8-Methyl-8-azabicyclo[3.2.1]oct-2-ene
1-[(methyl(4-cycloheptenyl)carbamoyl)oxy]-2(1H)-pyridinethione
α-chloronitrosocyclohexane
N-methyl-8-oxa-9-azabicyclo[3.2.2]non-6-ene

DownStream

8-Azabicyclo[3.2.1]octane-8-carboxylicacid, 3-oxo-, phenyl ester
8-Acetyl-8-azabicyclo[3.2.1]octane
8-azabicyclo[3.2.1]octane-8-carbaldehyde

Customs

[ HS Code ]: 2933990090

[ Summary ]:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

RNA-Seq Based De Novo Transcriptome Assembly and Gene Discovery of Cistanche deserticola Fleshy Stem.

PLoS ONE 10 , e0125722, (2015)

Cistanche deserticola is a completely non-photosynthetic parasitic plant with great medicinal value and mainly distributed in desert of Northwest China. Its dried fleshy stem is a crucial tonic in tra...

Identification and comparative analysis of microRNAs in barnyardgrass (Echinochloa crus-galli) in response to rice allelopathy.

Plant Cell Environ. 38 , 1368-81, (2015)

Rice allelopathy is a hot topic in the field of allelopathy, and behaviour of donor allelopathic rice has been well documented. However, few study addresses response of receiver barnyardgrass (BYG). W...

De novo RNA sequencing and transcriptome analysis of Colletotrichum gloeosporioides ES026 reveal genes related to biosynthesis of huperzine A.

PLoS ONE 10(3) , e0120809, (2015)

Huperzine A is important in the treatment of Alzheimer's disease. There are major challenges for the mass production of huperzine A from plants due to the limited number of huperzine-A-producing plant...

8-Methyl-8-azabicyclo[3.2.1]octane-3-thiol
2-amino-8-methyl-8-azabicyclo[3.2.1]octane
8-methyl-8-azabicyclo[3.2.1]octane-4,7-diol
3-Carboxy-8-methyl-8-azabicyclo[3.2.1]octane
4-methoxy-8-methyl-8-azabicyclo[3.2.1]octane
3-methoxy-8-methyl-8-azabicyclo[3.2.1]octane