iodoanisole

Suppliers

Names

[ CAS No. ]:
529-28-2

[ Name ]:
iodoanisole

[Synonym ]:
2-Iodophenol methyl ether
2-methoxyphenyl iodide
2-Iodoanisole
1-Iodo-2-methoxybenzene
Benzene,1-iodo-2-methoxy
2-Iodophenyl methyl ether
Benzene, 1-iodo-2-methoxy-
2-Methoxyiodobenzene
iodoanisole
o-methoxyiodobenzene
MFCD00001039
Anisole, o-iodo-
o-iodoanisole
o-Anisyl iodide
o-Methoxyphenyl iodide
EINECS 208-456-4

Chemical & Physical Properties

[ Density]:
1.7±0.1 g/cm3

[ Boiling Point ]:
244.9±0.0 °C at 760 mmHg

[ Melting Point ]:
8-10ºC

[ Molecular Formula ]:
C7H7IO

[ Molecular Weight ]:
234.034

[ Flash Point ]:
98.5±22.6 °C

[ Exact Mass ]:
233.954147

[ PSA ]:
9.23000

[ LogP ]:
3.28

[ Vapour Pressure ]:
0.0±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.592

[ Water Solubility ]:
insoluble

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
29093090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Anisole
  • 2-Anisidine
  • 2-Methoxyphenylboronic acid
  • bromoanisole
  • Methyl bromide
  • iodophenol
  • methyl iodide
  • LITHIUM TETRAMETHYLPIPERIDIDE

DownStream

  • 4-(2-methoxyphenyl)butan-1-ol
  • Methyl 2-methoxybenzoate
  • 1-allyl-2-methoxybenzene
  • 2,4-BPS
  • 1-Bromo-2-iodo-4-methoxybenzene
  • 2-Ethylbenzofuran
  • 2,3-dimethylbenzofuran
  • (2-Methoxyphenyl)acetaldehyde
  • 3-(2-Methoxyphenyl)-3-oxopropanenitrile
  • Ethyl benzoate

Customs

[ HS Code ]: 2909309090

[ Summary ]:
2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Palladium-catalyzed asymmetric Heck arylation of 2,3-dihydrofuran--effect of prolinate salts.

Dalton Trans. 42(4) , 1215-22, (2013)

Chiral ionic liquids (CILs) containing L-prolinate and L-lactate anions and non-chiral quaternary ammonium cations were employed in the palladium catalyzed enantioselective Heck arylation of 2,3-dihyd...

Synthesis of 2,3-disubstituted benzo[b]furans by the palladium-catalyzed coupling of o-iodoanisoles and terminal alkynes, followed by electrophilic cyclization.

J. Org. Chem. 70(25) , 10292-6, (2005)

[reaction: see text] 2,3-Disubstituted benzo[b]furans are readily prepared under very mild reaction conditions by the palladium/copper-catalyzed cross-coupling of various o-iodoanisoles and terminal a...


More Articles

Related Compounds

  • iodoanisole
  • 4-Iodoanisole
  • 3-iodoanisole
  • 3-Iodoanisole
  • 2,4-iodoanisole
  • 2,4-iodoanisole
  • [4-(2-Amino-ethyl)-bicyclo[2.2.2]oct-1-yl]-carbamic acid tert-butyl ester
  • 3-(3-(1-(2-((Pyridin-2-yl)methylamino)pyridin-4-yloxy)naphthalen-4-yl)ureido)-5-tert-butyl-2-methoxybenzoic acid
  • 3-((4-((4-((Tert-butoxycarbonyl)amino)naphthalen-1-yl)oxy)-pyridin-2-yl)amino)-5-methoxybenzoic acid
  • 5-(tert-Butyl)-2-methoxy-3-nitrobenzenesulfonamide
  • 1-(2-(2-(2-Methoxyethoxy)ethoxy)ethylsulfinyl)-3-methoxy-5-nitrobenzene
  • 5-(5-Tert-butyl-2-methoxy-3-nitrophenyl)-1h-1,2,3-triazole
  • Phenyl 3-(methoxycarbonyl)-5-tert-butyl-2-methoxyphenylcarbamate
  • 2-Benzyl-4-chloro-6-phenyl-1,3,5-triazine
  • 2-Chloro-4,6-dicyclohexyl-1,3,5-triazine
  • 5-(3-Methanesulfonylphenyl)-1,2-oxazol-3-amine
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