2-Methyl-2-propanyl bromoacetate

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Names

[ CAS No. ]:
5292-43-3

[ Name ]:
2-Methyl-2-propanyl bromoacetate

[Synonym ]:
Bromoacetic Acid tert-Butyl Ester
E1VOX1&1&1
2-Methyl-2-propanyl bromoacetate
tert-butyl 2-bromoacetate
tert-Butyl Bromoacetate
EINECS 226-133-6
Acetic acid, 2-bromo-, 1,1-dimethylethyl ester
Acetic acid, bromo-, 1,1-dimethylethyl ester
MFCD00000188
T-BUTYL 2-BROMOACETATE

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
164.0±8.0 °C at 760 mmHg

[ Molecular Formula ]:
C6H11BrO2

[ Molecular Weight ]:
195.054

[ Flash Point ]:
49.4±0.0 °C

[ Exact Mass ]:
193.994232

[ PSA ]:
26.30000

[ LogP ]:
2.07

[ Vapour Pressure ]:
2.0±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.457

[ Storage condition ]:
0-6°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R10;R36/37/38

[ Safety Phrases ]:
S26-S24/25-S16

[ RIDADR ]:
UN 1993 3/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3

[ HS Code ]:
2915709000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Bromoacetyl bromide
  • tert-Butanol
  • Bromoacetic acid
  • Isobutylene
  • Bromoacetyl chloride
  • tert-Butyl 2,2,2-trichloroacetimidate
  • Propane,2-iodo-2-methyl-
  • BROMOACETIC ANHYDRIDE

DownStream

  • tert-butyl 2-bromo-2-trimethylsilylacetate
  • tert-butyl 3,3-dicyanopropanoate
  • 3-(2-Hydroxyphenyl)propionate
  • Z-Asp(OtBu)-OH.H2O
  • Z-L-aspartic acid di-tert·butyl ester
  • (HYDROXYMETHYL)-2-PYRROLIDINONE
  • Di-tert-butyl succinate
  • Methylbenzylalcohol

Customs

[ HS Code ]: 2915900090

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

Articles

Gas chromatography with parallel hard and soft ionization mass spectrometry.

Rapid Commun. Mass Spectrom. 29(1) , 91-9, (2014)

Mass spectrometric identification of compounds in chromatography can be obtained from molecular masses from soft ionization mass spectrometry techniques such as field ionization (FI) and fragmentation...

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In clinical practice, it is difficult to identify tumor margins during brain surgery due to its inherent infiltrative character. Herein, a unique dual-modality nanoprobe (Gd-DOTA-Ag2S QDs, referred as...

Synthesis of fused heteroarylprolines and pyrrolopyrroles.

J. Org. Chem. 69 , 4656-4662, (2004)

Fused heteroarylprolines were prepared starting from 4-oxo-N-(PhF)proline benzyl ester (6, PhF = 9-(9-phenylfluorenyl)) following two approaches. First, allylation of oxoproline 6 followed by Wacker o...


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Related Compounds

  • 2-Methyl-2-propanyl (3-aminocyclobutyl)carbamate
  • 2-Methyl-2-Propanyl 5-Hydroxy-3,4-Dihydro-2(1H)-Isoquinolinecarboxylate
  • 2-Methyl-2-propanyl {[4'-(hydroxymethyl)-2-biphenylyl]methyl}carb amate
  • 2-Methyl-2-propanyl [3-phenyl-1-(phenylsulfonyl)propyl]carbamate
  • 2-Methyl-2-propanyl [(2S)-1-cyclopentyl-3-oxo-2-propanyl]carbamat e
  • 2-Methyl-2-propanyl (3-methyl-1-oxo-2-butanyl)carbamate
  • 6-Chloro-2-(difluoromethyl)benzo[b]thiophen-3-ol
  • 3-(3-Bromopyridin-2-yl)-2,2-dimethylpropanoic acid
  • 2L7Iav4ieh
  • 1-(Difluoromethyl)-2-ethynyl-4-fluorobenzene
  • 3-Oxo-1,2,3,4-tetrahydroisoquinoline-7-carboxylic acid
  • Methyl 2-(trifluoromethyl)oxazole-4-carboxylate
  • 2-(1-Amino-2-methoxyethyl)benzene-1,3-diol
  • 6-benzyl-2-(((2-(4-methoxyphenyl)-5-methyloxazol-4-yl)methyl)thio)-5,6,7,8-tetrahydropyrido[4,3-d]pyrimidin-4(3H)-one
  • (1R,2S)-1-Amino-1-(3,4-dichlorophenyl)propan-2-OL
  • 5-Cyclopropyl-2-(piperidin-3-yloxy)pyridine
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