Bis(tri-t-butylphosphine)palladium

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Names

[ CAS No. ]:
53199-31-8

[ Name ]:
Bis(tri-t-butylphosphine)palladium

[Synonym ]:
palladium,tritert-butylphosphane
palladium - tri-tert-butylphosphane (1:2)
Bis(tri-t-butylphosphine)palladium
Palladium - tri-tert-butylphosphine (1:2)
Pd(t-Bu3P)2
MFCD03094580
Bis(tri-t-butylphosphine)palladium(0)
Palladium - tris(2-methyl-2-propanyl)phosphine (1:2)
Phosphine, tris(1,1-dimethylethyl)-, palladium salt (2:1)

Chemical & Physical Properties

[ Boiling Point ]:
229.4ºC at 760mmHg

[ Melting Point ]:
>300 °C

[ Molecular Formula ]:
C24H54P2Pd

[ Molecular Weight ]:
511.05

[ Flash Point ]:
94.6ºC

[ Exact Mass ]:
510.273560

[ PSA ]:
27.18000

[ LogP ]:
9.72760

[ Storage condition ]:
Freezer

[ Water Solubility ]:
insoluble

MSDS

Click to get detail MSDS

Safety Information

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S24/25

[ RIDADR ]:
NONH for all modes of transport

Synthetic Route

Click to get detail synthetic route

Articles

Pd/P(t-Bu)(3): a mild and general catalyst for Stille reactions of aryl chlorides and aryl bromides.

J. Am. Chem. Soc. 124 , 6343, (2003)

Pd/P(t-Bu)(3) serves as an unusually reactive catalyst for Stille reactions of aryl chlorides and bromides, providing solutions to a number of long-standing challenges. An unprecedented array of aryl ...

Sequential assembly strategy for tetrasubstituted olefin synthesis using vinyl 2-pyrimidyl sulfide as a platform.

J. Am. Chem. Soc. 126 , 11778, (2004)

We have developed a programmable and diversity-oriented synthetic scheme for tetrasubstituted olefins through a site-selective and sequential assembly of pi-components onto a C=C core of vinyl 2-pyrim...

Aqueous hydroxide as a base for palladium-catalyzed amination of aryl chlorides and bromides.

J. Org. Chem. 67 , 6479, (2002)

The amination of aryl halides in the presence of inexpensive and air-stable alkali metal hydroxide bases and Pd[P(t-Bu)3]2 as catalyst gave arylamines in high yields. The reactions were conducted with...


More Articles

Related Compounds

  • bis(tri-t-butylphosphine)palladium
  • bis(tri-t-butylphosphine)platinum(0)
  • DICHLORO(CHLORODI-T-BUTYLPHOSPHINE)PALLADIUM(II) DIMER
  • Tri-t-butylphosphine[bis(trifluoromethyl)sulfonylimido]gold(I),
  • [(1,5-cyclooctadiene)PtCl(tri-t-butylphosphine)]Cl
  • tritert-butyl(tritert-butylstannylsulfanyl)stannane
  • 2-(1-methyl-5-propyl-1H-1,2,3-triazol-4-yl)acetonitrile
  • benzyl N-{6-[(2R,4R)-2-(aminomethyl)-4-hydroxypyrrolidin-1-yl]pyrimidin-4-yl}-N-methylcarbamate
  • 6-(2,2,2-Trifluoroacetyl)-6-azabicyclo[3.1.1]heptane-1-carboxylic acid
  • 6-[(Benzyloxy)carbonyl]-6-azabicyclo[3.1.1]heptane-1-carboxylic acid
  • (2R)-3-methyl-2-[2-(2,2,2-trifluoroacetamido)acetamido]butanoic acid
  • 5-(2,2,2-trifluoroacetyl)-4H,5H,6H,7H-pyrazolo[1,5-a]pyrazine-4-carboxylic acid
  • 3-Nitro-5-(trifluoromethyl)phenyl 4-methylbenzene-1-sulfonate
  • 5-Methoxy-5-methyl-1,3-oxazinan-2-one
  • 1,3-dioxo-2,3-dihydro-1H-isoindol-2-yl 2-(1-aminocyclopropyl)acetate
  • 5-Bromo-6-fluoro-N-methyl-2-benzoxazolamine
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