4-Bromo-3-nitrotoluene

Names

[ Name ]:
4-Bromo-3-nitrotoluene

[Synonym ]:
EINECS 226-203-6
MFCD00024180
1-Bromo-4-methyl-2-nitrobenzene
Benzene, 1-bromo-4-methyl-2-nitro-
4-Bromo-3-nitrotoluene

Chemical & Physical Properties

[ Density]:
1.6±0.1 g/cm3

[ Boiling Point ]:
252.2±20.0 °C at 760 mmHg

[ Melting Point ]:
31-33 °C(lit.)

[ Molecular Formula ]:
C₇H₆BrNO₂

[ Molecular Weight ]:
216.032

[ Flash Point ]:
106.3±21.8 °C

[ Exact Mass ]:
214.958176

[ PSA ]:
45.82000

[ LogP ]:
2.98

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.593

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R20/21/22;R36/37/38

[ Safety Phrases ]:
S26-S36-S36/37-S36/37/39-S22

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2904909090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

1-Amino-2-nitro-4-methylbenzene
3-Nitrotoluene
4-Bromotoluene
2-Nitro-p-acetotoluidide
Bromine

DownStream

Diazene,1,2-bis(3-methylphenyl)-
2-Bromo-5-methylbenzonitrile
1-bromo-4-(bromomethyl)-2-nitrobenzene
4-Bromo-3-fluorotoluene
3,3'-Bipyridyl
2,2'-dinitro-4,4'-dimethylbiphenyl
3-(4-methyl-2-nitro-phenyl)-pyridine
2-Fluoro-4-methylbenzoic acid
2-Bromo-5-methylaniline
4-Bromo-3-nitrobenzoic acid

Customs

[ HS Code ]: 2904909090

[ Summary ]:
HS:2904909090 sulphonated, nitrated or nitrosated derivatives of hydrocarbons, whether or not halogenated VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Biaryl Product Formation from Cross-coupling in Palladiumcatalyzed Borylation of a Boc Protected Aminobromoquinoline Compound. Fang H, et al.

Molecules 9(3) , 178-184, (2004)

Orientation effects in the diphenyl series. Part XII. The mono-and the di-nitration of 4: 4'-dimethyldiphenyl. Marler EEJ and Turner EE.

J. Chem. Soc. , 2391-2394, (1932)

1-Bromo-4-methyl-2-nitrobenzene. Li P, et al.

Acta Crystallogr. Sect. E Struct. Rep. Online 67(10) , 2641-2641, (2011)

4-Bromo-2-methyl-6-nitroaniline
4-bromo-3,6-dihydro-2H-thiopyran
4-Bromo-3,5-diiodopyridine-2-carboxylic acid
4-BROMO-3-FLUORO-3'-PIPERIDINOMETHYL BENZOPHENONE
4-Bromo-3-Methoxypicolinaldehyde
4-Bromo-3-chlorobenzamide
O-[1-(2-methylcyclopropyl)ethyl]hydroxylamine
Piperidine, 3-fluoro-4-methoxy-4-methyl-, (3R,4S)-rel-
1-Bromo-3-(methylamino)propan-2-one
1-(2-methylpropyl)-1H-1,2,3-benzotriazol-4-amine
3-(3,4,5-Trichlorophenyl)-1H-pyrazole
2-(2,2-Dimethylthiolan-3-yl)acetic acid
15,16-Secodammara-17(20),24-diene-15,16-dioic acid, 3-[[6-O-(6-deoxy-I+/--L-mannopyranosyl)-I(2)-D-glucopyranosyl]oxy]-21,22-dihydroxy-, 15,21:16,22-dilactone, (3I(2),14I(2),22R)-
2,2-Dibromo-5 inverted exclamation mark-chloro-2 inverted exclamation mark-nitroacetophenone
5-(2-Methoxyethoxy)-1-methyl-3-nitro-1H-pyrazole
(3I(2),4I(2),22I(2))-22-[[(2R)-3,4-Dihydro-5-hydroxy-6-methyl-4-oxo-2H-pyran-2-yl]oxy]-23-hydroxyolean-12-en-3-yl O-I(2)-D-glucopyranosyl-(1a2)-O-I+/--L-arabinopyranosyl-(1a2)-I(2)-D-glucopyranosiduronic acid

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