Benzyl acetylacetate

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Names

[ CAS No. ]:
5396-89-4

[ Name ]:
Benzyl acetylacetate

[Synonym ]:
CH3COCH2CO2Bn
Benzyl 3-oxobutyrate
FEMA 2136
Benzylacetoacetat
BENZYL2-OXOBUTANOATE
Benzyl 3-oxobutanoate
Acetoacetic Acid Benzyl Ester
EINECS 226-416-4
Benzyl acetylacetate
Benzyl β-ketobutyrate
Acetoacetic acid, benzyl ester
Butanoic acid, 3-oxo-, phenylmethyl ester
benzyloxycarbonylacetone
AC-BENZYL
Benzyl acetoacetate
Acetoacetic acid, benzyl ester (8CI)
phenylmethyl 3-oxobutanoate
MFCD00008785
Benzyl3-oxobutanoate

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
298.3±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C11H12O3

[ Molecular Weight ]:
192.211

[ Flash Point ]:
120.7±20.4 °C

[ Exact Mass ]:
192.078644

[ PSA ]:
43.37000

[ LogP ]:
2.03

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.509

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves

[ Hazard Codes ]:
Xi

[ Safety Phrases ]:
S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
1

[ HS Code ]:
2918300090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Methyl acetoacetate
  • Benzyl alcohol
  • Diketene
  • tert-Butyl acetoacetate
  • Ethyl acetoacetate
  • 1-acetylimidazole
  • Benzyl acetate
  • Phenethyl alcohol
  • 2-OXAZOLIDINONE, 3-ACETYL-
  • Benzyl bromoacetate

DownStream

  • benzyl 3-oxo-2-(phenylhydrazinylidene)butanoate
  • 2,5,6-Trimethyl-1H-benzimidazole
  • oxazolidinone
  • benzyl 3-((trimethylsilyl)oxy)but-2-enoate
  • 3-Methyl-3-pyrazolin-5-one
  • Benzyl acetate
  • benzyl (Z)-3-dimethoxyphosphoryloxybut-2-enoate
  • Benzyl 4-acetyl-3,5-dimethyl-1H-pyrrole-2-carboxylate
  • Acetoacetic Acid
  • 2-Methyl-1H-benzo[d]imidazole

Customs

[ HS Code ]: 2918300090

[ Summary ]:
2918300090 other carboxylic acids with aldehyde or ketone function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles

Asymmetric bioreduction of benzyl acetoacetate to its corresponding alcohol, benzyl (S)-(+)-3-hydroxybutyrate by the yeast Candida schatavii strain 1831. Chartrain M, et al.

J. Ferment. Bioeng. 82(5) , 507-508, (1996)


More Articles

Related Compounds

  • Benzyl 2-chloro-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenylcarbamate
  • benzyl 4-ethynyl-3,5-dimethylpyrrole-2-carboxylate
  • Benzyl-((E)-2-nitro-1-phenyl-vinyl)-phenyl-amine
  • benzyl 2-methylpiperazine-1-carboxylate,hydrochloride
  • benzyl-arsine
  • benzyl 2-bromocyclopropylideneacetate
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 1,4,5,6-Tetrahydro-N-[1-(3-methoxyphenyl)ethyl]-6-oxo-3-pyridazinecarboxamide
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 3-(1-Methoxypropan-2-ylamino)pyridine-4-carboxylic acid
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • 2-Amino-3-(pyridin-4-YL)propanamide
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde