Bis(2-bromoethyl) ether

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Names

[ Name ]:
Bis(2-bromoethyl) ether

[Synonym ]:
MFCD00039196
1-Bromo-2-(2-bromoethoxy)ethane
2-Bromoethyl ether
2,2-Dibromodiethyl Ether
Ethane, 2,2'-oxybis[1-bromo-
2,2'-Dibromodiethyl Ether
2,2'-Dibromoethylether
Ether, bis(2-bromoethyl)
Ether, bis(2-bromoethyl) (8CI)
Ethane, 1,1'-oxybis[2-bromo-
Bis(2-bromoethyl) ether
DI(2-BROMOETHYL)ETHER
EINECS 226-504-2

Chemical & Physical Properties

[ Density]:
1.8±0.1 g/cm3

[ Boiling Point ]:
216.3±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C₄H₈Br₂O

[ Molecular Weight ]:
231.914

[ Flash Point ]:
85.0±0.0 °C

[ Exact Mass ]:
229.894180

[ PSA ]:
9.23000

[ LogP ]:
1.87

[ Vapour Pressure ]:
0.2±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.506

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H315-H318-H335

[ Precautionary Statements ]:
P261-P280-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
T:Toxic;

[ Risk Phrases ]:
R61;R37/38;R41

[ Safety Phrases ]:
S53-S26-S36/37/39-S45

[ RIDADR ]:
2810

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1

[ HS Code ]:
2909199090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2909199090

[ Summary ]:
2909199090. other acyclic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

Asymmetric synthesis of functionalized diarylmethanols catalyzed by a new gamma-amino thiol.

J. Org. Chem. 71(2) , 833-5, (2006)

[reaction: see text] A mild asymmetric arylation of aromatic aldehydes catalyzed by gamma-amino thiol 5 gave the corresponding diarylmethanols with 95 to >99.5% ee.

J. Chem. Soc. Chem. Commun. , 1550, (1992)

J. Chem. Soc., Perkin Trans. II , 1213, (1989)