Titanium(4+) tetrapropan-2-olate

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Names

[ CAS No. ]:
546-68-9

[ Name ]:
Titanium(4+) tetrapropan-2-olate

[Synonym ]:
Titanium(IV) Isopropoxide
Titanium(4+) tetra(2-propanolate)
TITANIUM ISOPROPOXIDE
titanium(4+)salt
EINECS 208-909-6
Titanium(IV) isoprop
VERTEC(TM) TIPT
Titaniumispropoxide
titanium(IV) isopropylate
2-Propanol, titanium(4+) salt (4:1)
Ti(OCH(CH3)2)4
tyzortpt
MFCD00008871
Titanium(4+) tetrapropan-2-olate
TITANIUM ISO-PROPYLATE
tiisopropylate
ISOPROPYL TITANATE
Iso-propy titanate

Chemical & Physical Properties

[ Density]:
0.96 g/mL at 20 °C(lit.)

[ Boiling Point ]:
232 °C(lit.)

[ Melting Point ]:
14-17 °C(lit.)

[ Molecular Formula ]:
C12H28O4Ti

[ Molecular Weight ]:
284.215

[ Flash Point ]:
72 °F

[ Exact Mass ]:
284.146698

[ PSA ]:
36.92000

[ LogP ]:
3.50280

[ Index of Refraction ]:
n20/D 1.464(lit.)

[ Storage condition ]:
Flammables area

[ Stability ]:
Stable, but decomposes in the presence of moisture. Incompatible with aqueous solutions, strong acids, strong oxidizing agents. Flammable.

[ Water Solubility ]:
HYDROLYSIS

[ Freezing Point ]:
14.8℃

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
NT8060000
CHEMICAL NAME :
Isopropyl alcohol, titanium(4+) salt
CAS REGISTRY NUMBER :
546-68-9
LAST UPDATED :
199701
DATA ITEMS CITED :
7
MOLECULAR FORMULA :
C3-H8-O.1/4Ti
MOLECULAR WEIGHT :
72.07
WISWESSER LINE NOTATION :
3O-TI-O3&O3&O3

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1263,1986
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1263,1986 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
7460 uL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 28,313,1974
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>16 mL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 28,313,1974 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 83587 No. of Facilities: 150 (estimated) No. of Industries: 8 No. of Occupations: 30 No. of Employees: 9667 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 83587 No. of Facilities: 601 (estimated) No. of Industries: 15 No. of Occupations: 26 No. of Employees: 13193 (estimated) No. of Female Employees: 2925 (estimated)

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H319-H336

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P337 + P313-P403 + P235

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R10;R36

[ Safety Phrases ]:
S16-S26-S36/37/39

[ RIDADR ]:
UN 2413 3/PG 3

[ WGK Germany ]:
2

[ RTECS ]:
NT8060000

[ Packaging Group ]:
III

[ Hazard Class ]:
3

[ HS Code ]:
29051900

Synthetic Route

Precursor & DownStream

Precursor

  • Titanium tetrachloride
  • Isopropanol
  • Sodium isopropoxide
  • titanium
  • diisopropoxy-bis(N,N-diethylamine-N-carbodithioato)titanium(IV)
  • 2-(METHYLSULFINYL)ETHANAMINE HYDROCHLORIDE
  • ch3cho

DownStream

  • 11-(1-Piperazinyl)dibenzo[b,f][1,4]thiazepine
  • Isopropanol
  • Isopropyl Benzoate
  • 2-(METHYLSULFINYL)ETHANAMINE HYDROCHLORIDE
  • Benzenepropanoic acid,1-methylethyl ester
  • Ethyl Isopropyl Ether
  • 2,3-diethoxybutane
  • sec-Butylisopropyl ether
  • Methacrylic acid
  • 2-Methylbutyric acid

Customs

[ HS Code ]: 29051900

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  • titanium(4+) 2-propenolate
  • titanium(4+) 2-chloroethanolate
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  • titanium(4+) 2-ethoxyethanolate
  • titanium(4+) 2-aminoethanolate
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  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
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  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
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