Copper(I) bromide-dimethyl sulfide

Names

[ CAS No. ]:
54678-23-8

[ Name ]:
Copper(I) bromide-dimethyl sulfide

[Synonym ]:
MFCD00043295
EINECS 259-292-5
bromocopper,methylsulfanylmethane

Chemical & Physical Properties

[ Boiling Point ]:
29.5ºC at 760 mmHg

[ Melting Point ]:
132 °C (dec.)(lit.)

[ Molecular Formula ]:
C₂H₆BrCuS

[ Molecular Weight ]:
205.58400

[ Exact Mass ]:
203.86700

[ PSA ]:
25.30000

[ LogP ]:
1.82230

MSDS

Safety Information

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
26-36-24/25

[ RIDADR ]:
1759

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
8

Precursor & DownStream

Precursor

DownStream

Articles

1,1-Dibromo-1-alkenes as valuable partners in the copper-catalyzed direct alkynylation of azoles.

Org. Lett. 12 , 4038, (2010)

The copper-catalyzed direct alkynylation of azoles with 1,1-dibromo-1-alkenes as electrophiles is described. These easily accessible substrates are a useful addition to the field of direct alkynylatio...

Enantioselective Cu-catalyzed 1,4-addition of Grignard reagents to cyclohexenone using taddol-derived phosphine-phosphite ligands and 2-methyl-THF as a solvent.

Angew. Chem. Int. Ed. Engl. 47 , 7718, (2008)

Organic Synth. 83 , 80, (2006)

(trimethylstannyl)copper(I)-dimethyl sulfide
dms
copper(I) chloride, dimethylsulfide complex
Copper(1+) sulfidocopper
copper bromide
copper(I) dimethyldithiooxamide bromide
4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
5-Amino-7-bromo-2,3-dihydro-1H-inden-1-one
1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
(4-Methyl-tetrahydro-furan-2-yl)-methanol
8-(2,3-dihydro-1,4-benzodioxine-2-carbonyl)-3-(1H-1,2,3-triazol-1-yl)-8-azabicyclo[3.2.1]octane
N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
N-[1-(5-fluoropyridine-3-carbonyl)azetidin-3-yl]pyrimidin-4-amine
4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde