(1,5-Cyclohexadien-1-yloxy)(trimethyl)silane

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Names

[ CAS No. ]:
54781-19-0

[ Name ]:
(1,5-Cyclohexadien-1-yloxy)(trimethyl)silane

[Synonym ]:
(1,5-Cyclohexadien-1-yloxy)(trimethyl)silane
(Cyclohexa-1,5-dien-1-yloxy)(trimethyl)silane
1,3-Cyclohexadiene, 2-[(trimethylsilyl)oxy]-
MFCD00274202
cyclohexa-1,5-dien-1-yloxy(trimethyl)silane

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
187.6±8.0 °C at 760 mmHg

[ Molecular Formula ]:
C9H16OSi

[ Molecular Weight ]:
168.308

[ Flash Point ]:
58.7±8.7 °C

[ Exact Mass ]:
168.097046

[ PSA ]:
9.23000

[ LogP ]:
3.44

[ Vapour Pressure ]:
0.9±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.465

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F+

[ Risk Phrases ]:
10

[ Safety Phrases ]:
16

[ RIDADR ]:
UN 1993 3/PG 3

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Chlorotrimethylsilane
  • cyclohexenone
  • Diisopropylamine
  • Trimethylsilyl trifluoromethanesulfonate

DownStream

  • 4'-Nitro-4-biphenylol
  • 2-(4-Hydroxyphenyl)pyridine
  • bicyclo[2.2.2]octane-2,5-dione
  • Trimethyl Phenoxysilane
  • 2,3-Dioxabicyclo[2.2.2]oct-5-ene, 5-[(trimethylsilyl)oxy]
  • 2-[N-(diphenylphosphinothioylamino)-C-methylcarbonimidoyl]thiophene
  • 4-(Pyridin-3-yl)phenol
  • 3'-Nitro-[1,1'-biphenyl]-4-ol
  • ACETIC ACID 2-OXO-CYCLOHEX-3-ENYL ESTER
  • 3-benzoylcyclohexan-1-one

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

2-azabicyclo[2.2.2]octa-3,5-dione via a nitrile Diels-Alder reaction.

J. Org. Chem. 68(21) , 8256-7, (2003)

The hetero-Diels-Alder reaction of an electron-deficient nitrile, p-toluenesulfonyl cyanide, with the silyl enol ether of cyclohexenone produced a hydrolytically sensitive [4 + 2] adduct in good yield...

High-Temperature Diels-Alder Reactions: Transfer from Batch to Continuous Mode. Abele S, et al.

Org. Process Res. Dev. 16(5) , 1114-1120, (2011)

Design and Scale-Up of Diels-Alder Reactions for the Practical Synthesis of 5-Phenylbicyclo [2.2. 2] oct-5-en-2-one. Funel JA, et al.

Org. Process Res. Dev. 15(6) , 1420-1427, (2011)


More Articles

Related Compounds

  • 1-trimethylsiloxycyclopentene
  • 1,1-dimethoxyocta-1,3-dien-3-yloxy(trimethyl)silane
  • 1,1-dimethoxyhexa-1,3-dien-3-yloxy(trimethyl)silane
  • 1,1-Dimethoxy-3-(triMethylsiloxy)-1,3-butadiene
  • cyclooct-4-en-1-yloxy(trimethyl)silane
  • 2,3-dihydrofluoranthen-1-yloxy(trimethyl)silane