tert-Butyldimethylsilylimidazole

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Names

[ CAS No. ]:
54925-64-3

[ Name ]:
tert-Butyldimethylsilylimidazole

[Synonym ]:
tert-butyl-imidazol-1-yl-dimethylsilane
EINECS 259-398-1
1-[Dimethyl(2-methyl-2-propanyl)silyl]-1H-imidazole
tert-Butyldimethylsilylimidazole
MFCD00011682
1-[tert-Butyl(dimethyl)silyl]-1H-imidazole
1H-Imidazole, 1-[(1,1-dimethylethyl)dimethylsilyl]-
1-(t-Butyldimethylsilyl)-1H-Imidazole

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
251.6±9.0 °C at 760 mmHg

[ Molecular Formula ]:
C9H18N2Si

[ Molecular Weight ]:
182.338

[ Flash Point ]:
99.4±0.0 °C

[ Exact Mass ]:
182.123932

[ PSA ]:
17.82000

[ LogP ]:
2.35

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.471

[ Storage condition ]:
Refrigerator

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36-S45-S36/37/39-S16-S53

[ RIDADR ]:
UN 2922 8/PG 3

[ WGK Germany ]:
3

[ HS Code ]:
2933290090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Imidazole
  • tert-butyldimethylsilyl trichloroacetate
  • tert-Butyldimethylsilyl chloride
  • 1H-Imidazole, silver(1+) salt
  • N,N-Dimethyl-1H-imidazole-1-sulfonamide
  • tert-Butyldimethylsilyl Trifluoromethanesulfonate

DownStream

  • [tert-butyl(dimethyl)silyl] undec-10-enoate
  • Silane, (1,1-dimethylethyl)dimethyl(1-phenylpropoxy)-
  • acetic acid,tert-butyl-hydroxy-dimethylsilane
  • benzoic acid,tert-butyl-hydroxy-dimethylsilane
  • tert-butyl-dimethyl-(2-phenylethoxy)silane
  • tert-butyl-dimethyl-octoxysilane
  • tert-butyl-dimethyl-phenoxysilane

Customs

[ HS Code ]: 2933290090

[ Summary ]:
2933290090. other compounds containing an unfused imidazole ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Use of an 18O2 inhalation technique and mass isotopomer distribution analysis to study oxygenation of cholesterol in rat. Evidence for in vivo formation of 7-oxo-, 7 beta-hydroxy-, 24-hydroxy-, and 25-hydroxycholesterol.

J. Biol. Chem. 270(35) , 20278-84, (1995)

Cholesterol oxidation products (oxysterols) have been detected in many different tissues, often at concentrations 10(3) to 10(4) times lower than cholesterol. This constitutes a considerable risk of q...

Gas-liquid chromatography-mass spectrometry of mono- and dithiols as their tert.-butyldimethylsilyl derivatives.

J. Chromatogr. A. 483 , 21-32, (1989)

The use of gas-liquid chromatography and mass spectrometry with derivatizing agents that give stable derivatives and consistent fragmentation patterns allows for accurate identification of a variety o...

Steroid-hindered 17 beta-tertiary alcohol: characterization of dehydrated compounds.

Steroids 61(6) , 349-53, (1996)

Five dehydrated compounds obtained from a tert-butyldimethylsilylchloride/imidazole or an aqueous hydrochloric acid treatment of 17 alpha-butyl-3-O-methyl estradiol in refluxing solvent were purified ...


More Articles

Related Compounds

  • tert-Butyl 4-iodopicolinate
  • tert-butyl-hex-5-enoxy-dimethylsilane
  • tert-butyl-[2-(1H-indol-3-yl)ethoxy]-dimethylsilane
  • TERT-BUTYL-(2S,4R)-N'-(BENZYLOXYCARBONYL)-N'-(BENZYLOXYCARBONYL)-4-HYDROXYORNITHINATE
  • tert-butyl-dimethyl-[4-(1-phenylethenyl)phenoxy]silane
  • tert-butyl cyano(3,5-dichloro-2 pyridinyl)acetate
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • [5-(1,3-Dioxolan-2-yl)-2-fluorophenyl]methanamine
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 2-Fluoro-5-methoxy-N-methylbenzene-1-sulfonamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine