9-Bromo-9-phenylfluorene

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Names

[ CAS No. ]:
55135-66-5

[ Name ]:
9-Bromo-9-phenylfluorene

[Synonym ]:
9H-Fluorene, 9-bromo-9-phenyl-
9-bromanyl-9-phenyl-fluorene
9-phenyl-9-fluorenyl bromide
9-Bromo-9-phenyl-9H-fluorene
9-brom-9-phenyl-9h-fluoren
MFCD00075522
9-phenyl-9-bromofluorene
9-phenyl-9H-fluoren-9-yl bromide

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
394.3±41.0 °C at 760 mmHg

[ Melting Point ]:
99-101 °C(lit.)

[ Molecular Formula ]:
C19H13Br

[ Molecular Weight ]:
321.211

[ Flash Point ]:
172.5±17.3 °C

[ Exact Mass ]:
320.020050

[ LogP ]:
5.57

[ Vapour Pressure ]:
0.0±0.9 mmHg at 25°C

[ Index of Refraction ]:
1.688

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S27-S28-S36/37/39-S45

[ RIDADR ]:
UN 3261 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
2903999090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 9H-Fluorene, 9-phenyl-
  • Acetyl bromide
  • 9-Phenyl-9-fluorenol
  • Tritanol
  • Bromine

DownStream

  • 9-phenylfluorene-9-carboxylic acid
  • (4R, 2S)-4-Hydroxy-1-(9-phenyl-9H-fluoren-9-yl)-proline Methyl Ester
  • 9H-Fluorene,9-chloro-9-phenyl-
  • 1-(9-phenylfluoren-9-yl)imidazole
  • (2S)-4-Oxo-1-(9-phenylfluorenyl)-proline Methyl Ester
  • ethyl 2-bromoacetate
  • 9-Phenyl-9-fluorenol
  • 9-(9H-fluoren-9-yl)-9-phenylfluorene
  • 9H-Fluorene, 9-phenyl-

Customs

[ HS Code ]: 2903999090

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Configurational stability of N-protected. alpha.-amino aldehydes. Lubell WD and Rapoport H.

J. Am. Chem. Soc. 109(1) , 236-9, (1987)

Surrogates for Chiral Aminomalondialdehyde. Synthesis of N-(9-Phenylfluoren-9-yl) serinal and N-(9-Phenylfluoren-9-yl) vinylglycinal. Lubell WD and Rapoport H.

J. Org. Chem. 54(16) , 3824-31, (1989)

Synthesis of 5-substituted 1-hydroxypyrazoles through directed lithiation of 1-(benzyloxy) pyrazole. Vedso P and Begtrup M.

J. Org. Chem. 60(16) , 4995-98, (1995)


More Articles

Related Compounds

  • 9-bromo-9-methyl-fluorene
  • 9-bromo-9-(dimethylsulfonio)-9-borabicyclo[3.3.1]nonan-9-uide
  • 9-Bromo-9,10-dihydro-9,10-ethenoanthracene
  • 9-bromo-9,10-dihydro-9,10-ethano-anthracene-11,12-dicarboxylic acid-anhydride
  • 9-Bromo-9-[bromo(phenyl)methyl]-9H-fluorene
  • 9-bromo-9-bromomethyl-fluorene
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 2-(6-Amino-3-(aminomethyl)-5-(difluoromethyl)pyridin-2-yl)acetic acid
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 3-(2-Hydroxy-3-methoxypropyl)-4(3H)-quinazolinone