Dimethylprotoporphyrin IX dimethyl ester

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Names

[ CAS No. ]:
5522-66-7

[ Name ]:
Dimethylprotoporphyrin IX dimethyl ester

[Synonym ]:
Dimethyl 3,3'-(3,7,12,17-tetramethyl-8,13-divinyl-2,18-porphyrindiyl)dipropanoate
Protoporphyrin IX dimethyl ester (VAN)
7,12-Diethenyl-3,8,13,17-tetramethyl-21H,23H-porphine-2,18-dipropanoic Acid Dimethyl Ester
Dimethyl 7,12-diethenyl-3,8,13,17-tetramethyl-21H,23H-porphine-2,18-dipropanoate
Protoporphyrin ix dimethyl ester
Protoporphyrin IX Methyl Ester
Protoporphyrin Dimethyl Ester
Dimethyl 3,3'-(3,7,12,17-tetramethyl-8,13-divinylporphyrin-2,18-diyl)dipropanoate
Protoporphyrin IX Di-Me Ester
21H,23H-Porphine-2,18-dipropanoic acid, 7,12-diethenyl-3,8,13,17-tetramethyl-, dimethyl ester

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
1017.0±65.0 °C at 760 mmHg

[ Melting Point ]:
225-228ºC

[ Molecular Formula ]:
C36H38N4O4

[ Molecular Weight ]:
590.711

[ Flash Point ]:
568.8±34.3 °C

[ Exact Mass ]:
590.289307

[ PSA ]:
108.90000

[ LogP ]:
8.21

[ Vapour Pressure ]:
0.0±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.630

[ Storage condition ]:
2~8°C

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3.0

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • dibenzyl 3,3'-bis-(2-methoxycarbonylethyl)-4,4'-dimethyl-2,2'-methylenedipyrrole-5,5'-dicarboxylate
  • 3,3'-di(2-methoxycarbonylethyl)-4,4'-dimethyl-2,2'-dipyrrylmethane-5,5'-dicarboxylic acid
  • [5,5'-diformyl-4,4'-dimethyl-3,3'-bis[2-(methoxycarbonyl)ethyl]-2,2'-dipyrryl]methane
  • Benzyl 4-acetyl-3,5-dimethyl-1H-pyrrole-2-carboxylate
  • benzyl 4-(2-bromoethyl)-3,5-dimethylpyrrole-2-carboxylate
  • benzyl 4-ethynyl-3,5-dimethylpyrrole-2-carboxylate
  • benzyl 4-(1-chlorovinyl)-3,5-dimethylpyrrole-2-carboxylate
  • benzyl 4-(bromoacetyl)-3,5-dimethylpyrrole-2-carboxylate
  • benzyl 4-(3-methoxy-3-oxopropyl)-3,5-dimethyl-1H-pyrrole-2-carboxylate
  • benzyl-5-(acetoxymethyl)-4-[2-(methoxycarbonyl)ethyl]-3-methylpyrrole-2--carboxylate

DownStream

  • Dimethyl succinate
  • Protoporphyrin IX
  • methyl 3-[8,13-diformyl-18-(3-methoxy-3-oxopropyl)-3,7,12,17-tetramethyl-22,23-dihydroporphyrin-2-yl]propanoate
  • photoporphyrin A
  • isophotoprotoporphyrin-IX dimethyl ester
  • 21H,23H-Porphine-2,18-dipropanoicacid, 7,12-diethyl-3,8,13,17-tetramethyl-, 2,18-dimethyl ester
  • Hematoporphyrin
  • 3(2),3(2),8(2),8(2)-tetrafluoroprotoporphyrin dimethyl ester

Articles

Observation of heme transfer from cytochrome b5 to DNA aptamer.

Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 96 , 365-9, (2012)

Heme transfer is commonly observed from one heme protein to the other such as from cytochrome b(5) (cyt b(5)) to apo-myoglobin. In this study, instead of to another heme protein, we observed the heme ...

Direct electrochemistry and spectroelectrochemistry of osmium substituted horseradish peroxidase.

Bioelectrochemistry 76(1-2) , 28-33, (2009)

In this contribution the substitution of the central protoporphyrin IX iron complex of horseradish peroxidase by the respective osmium porphyrin complex is described. The direct electrochemical reduct...

Comparison of binding ability and location of two mesoporphyrin derivatives in liposomes explored with conventional and site-selective fluorescence spectroscopy.

J. Phys. Chem. B 116(32) , 9644-52, (2012)

Application of porphyrins as photosensitizers is based on their light-triggered generation of reactive oxygen species (ROS) that may cause oxidative tissue damage and ultimately kill cells. Cellular m...


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