methylthiol

Suppliers

Names

[ CAS No. ]:
554-14-3

[ Name ]:
methylthiol

[Synonym ]:
2-Methyl-thiophene
2-methlthiophene
2-thiotolene
2-Me-thiophene
2-METHYLTHIOPHENE GC
2-Methylthiophene
5-Methylthiophene
UNII-7115JAP77A
EINECS 209-063-0
α-Methylthiophene
methylthiophene
MFCD00005451
methylthiol
Thiophene,2-methyl
2MT
Thiophene, 2-methyl-
2-methyl-thiophen

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
107.9±3.0 °C at 760 mmHg

[ Melting Point ]:
−63 °C(lit.)

[ Molecular Formula ]:
C5H6S

[ Molecular Weight ]:
98.166

[ Flash Point ]:
7.2±0.0 °C

[ Exact Mass ]:
98.019020

[ PSA ]:
28.24000

[ LogP ]:
2.36

[ Vapour Pressure ]:
31.0±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.531

[ Storage condition ]:
Flammables area

[ Water Solubility ]:
immiscible

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
XM9625000
CHEMICAL NAME :
Thiophene, 2-methyl-
CAS REGISTRY NUMBER :
554-14-3
BEILSTEIN REFERENCE NO. :
0103734
LAST UPDATED :
199710
DATA ITEMS CITED :
8
MOLECULAR FORMULA :
C5-H6-S
MOLECULAR WEIGHT :
98.17
WISWESSER LINE NOTATION :
T5SJ B1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
3200 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,87,1982
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,87,1982
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1460 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,87,1982
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
11500 mg/m3/2H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,87,1982
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Mammal - species unspecified
DOSE/DURATION :
1260 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 51(5),61,1986 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 20 mg/m3 JAN 1993

Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225

[ Precautionary Statements ]:
P210

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F:Flammable;Xi:Irritant;

[ Risk Phrases ]:
R11;R36/37/38

[ Safety Phrases ]:
S16-S37/39-S26

[ RIDADR ]:
UN 1993 3/PG 2

[ WGK Germany ]:
3

[ RTECS ]:
XM9625000

[ Packaging Group ]:
II

[ Hazard Class ]:
3

[ HS Code ]:
29349990

Synthetic Route

Precursor & DownStream

Precursor

  • 2-(Tributylstannyl)Thiophene
  • methyl iodide
  • Thiophen-2-ylmethanol
  • pentanethiol
  • UNII:K290J6114Q
  • carbon monoxide
  • Thiophene(SIV)
  • 2-Thiophenecarboxaldehyde
  • trans-1,3-pentadiene
  • 5-Methylthiophene-2-boronic acid pinacol ester

DownStream

  • 2-Methyl-3-nitrothiophene-5-carboxylic Acid
  • 5-Methylthiophene-2-boronic acid pinacol ester
  • 1-(5-Methylthien-2-yl)propan-1-one
  • ETHYL 5-METHYLTHIOPHENE-2-GLYOXYLATE
  • 2-Ethyl-5-methylthiophene
  • Thiophene-2-carboxylic acid
  • Tetrabromothiophene
  • 2-(Bromomethyl)thiophene
  • 1-[1-(5-methylthiophen-2-yl)-2-(4-nitrophenyl)ethyl]imidazole
  • 4-(5-METHYL-2-THIENYL)-4-OXOBUTYRIC ACID

Customs

[ HS Code ]: 29349990

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Related Compounds

  • 9-Fluorenyl methylthiol
  • thiophene-3-methylthiol
  • 2-(Methylthiol-d3)-bromobenzene
  • 3-(Methylthiol-d3)-bromobenzene
  • 2-GIANIDINOTHIAZOLE-4-METHYLTHIOL
  • 2-methyl-5-(methylthiol)-Thiophene
  • 5-[(4-Methylbenzenesulfonyl)oxy]pyridine-2-carboxylic acid
  • 4-methyl-6-(morpholin-2-yl)-3,4-dihydro-2H-1,4-benzoxazine
  • 2,2-Difluoro-2-[2-(trifluoromethyl)-1,3-thiazol-4-yl]ethan-1-ol
  • 3-amino-2-cycloheptyl-N-methylpropanamide
  • 2-Methyl-1-phenylpropan-2-yl 4-methylbenzene-1-sulfonate
  • 1-[2-(2,5-Difluoro-4-nitrophenyl)ethyl]cyclopropan-1-amine
  • (2R)-6-(1,3-benzothiazol-2-yl)hexan-2-ol
  • 4-Amino-4-(1-methoxypropyl)cyclohexan-1-ol
  • [2,2-dimethyl-3-(1-methyl-1H-indol-5-yl)cyclopropyl]methanamine
  • Tert-butyl 4-{methyl[4-(trifluoromethanesulfonyloxy)pyrimidin-2-yl]amino}piperidine-1-carboxylate
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