3-Methyl-2-buten-1-ol

Suppliers

Names

[ CAS No. ]:
556-82-1

[ Name ]:
3-Methyl-2-buten-1-ol

[Synonym ]:
Prenyl alcohol
MFCD00002916
2-Buten-1-ol, 3-methyl-
EINECS 209-141-4
3,3-Dimethylallyl alcohol
UNII-55MY0HM445
γ,γ-Dimethylallyl alcohol
Prenol
3-Methyl-2-butene-1-ol
Q2UY1&1
3-Methylbut-2-en-1-ol
3-Methyl-2-butenol
3-Methyl-2-butenyl alcohol
3-Methyl-2-buten-1-ol
2-Methyl-2-buten-4-ol

Chemical & Physical Properties

[ Density]:
0.848

[ Boiling Point ]:
140 ºC

[ Melting Point ]:
-86ºC

[ Molecular Formula ]:
C5H10O

[ Molecular Weight ]:
86.132

[ Flash Point ]:
43 ºC

[ Exact Mass ]:
86.073166

[ PSA ]:
20.23000

[ LogP ]:
1.24

[ Vapour Pressure ]:
2.4±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.442-1.444

[ Storage condition ]:
Flammables area

[ Water Solubility ]:
170 g/L (20 ºC)

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
EM9472500
CHEMICAL NAME :
2-Buten-1-ol, 3-methyl-
CAS REGISTRY NUMBER :
556-82-1
BEILSTEIN REFERENCE NO. :
1633479
LAST UPDATED :
199710
DATA ITEMS CITED :
6
MOLECULAR FORMULA :
C5-H10-O
MOLECULAR WEIGHT :
86.15
WISWESSER LINE NOTATION :
Q2UY1&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 17,895,1979 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
810 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 17,895,1979
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
3900 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 17,895,1979

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H302-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R10;R21/22;R38

[ Safety Phrases ]:
S26-S36-S37-S23-S16

[ RIDADR ]:
UN 1987 3/PG 3

[ WGK Germany ]:
1

[ RTECS ]:
EM9472500

[ Packaging Group ]:
III

[ Hazard Class ]:
3

[ HS Code ]:
2905290000

Synthetic Route

Precursor & DownStream

Precursor

  • 3-Methyl-2-butenal
  • Ethyl 3-methyl-2-butenoate
  • 3,3-Dimethylacrylic acid
  • 3,3-Dimethylallyl bromide
  • ISOPRENOL
  • 2-(3-methylbut-2-enoxy)oxane
  • (E)-3-tributylstannanyl-but-2-en-1-ol
  • methyl iodide
  • Cyclohexanone
  • 2-Methyl-3-buten-2-ol

DownStream

  • 2,3-EPOXY-3-METHYLBUTYLESTER-4-NITROBENZOATE
  • 7-Prenylumbelliferone
  • 3-methylbut-2-enyl 2,2,2-trichloroethanimidate
  • 2,3-dibromo-3-methylbutan-1-ol
  • 1-Chloro-3-methyl-2-butene
  • 3-Methyl-2-butenal
  • 3-CHLORO-3-METHYL-1-BUTENE
  • Isoamyl ether
  • 5-methylhex-4-en-1-ol
  • 3-methylbut-2-enyl 3-oxobutanoate

Customs

[ HS Code ]: 2905290000

[ Summary ]:
2905290000 unsaturated monohydric alcohols。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

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Related Compounds

  • 3-Methyl-2-buten-1-ol
  • 2-ISOPENTYL-3-METHYL-2-BUTEN-1-OL
  • 2-ISOPENTYL-3-METHYL-2-BUTEN-1-OL
  • (E)-4-bromo-3-methyl-2-buten-1-ol
  • 3-methyl-2-buten-1-ol benzyl ether
  • (E)-4-chloro-3-methyl-2-buten-1-ol
  • Propyl 2-(4-propylsulfanylphenyl)acetate
  • Ethyl 4-ethoxy-1-(4-fluoro-2-methyl-phenyl)pyrazole-3-carboxylate
  • N-[2-(Cyclopropylamino)ethyl]-N-methylcyclopropanamine
  • 5-(4-Methylpiperazin-1-yl)pyrimidine-2-carbonitrile
  • Methanesulfonic acid 2-(3-ethoxycarbonylamino-phenyl)-ethyl ester
  • 2-[(Cyclopropylmethyl)amino]-N-4-pyridinylacetamide
  • N,N-Dimethyl-1-(piperidin-4-yl)-1H-1,2,3-triazole-4-carboxamide
  • Methyl 3-(1,1-difluoroethyl)benzoate
  • 2-Bromo-6-(5-(dimethylamino)-1-oxoisoindolin-2-yl)benzyl Acetate
  • Methyl 2,2-dimethyl-4-(5-(4-nitrophenyl)thiazol-2-yl)butanoate