Nitroguanidine

Suppliers

Names

[ CAS No. ]:
556-88-7

[ Name ]:
Nitroguanidine

[Synonym ]:
EINECS 209-143-5
2-nitroguanidine
MFCD00007039

Chemical & Physical Properties

[ Density]:
2.0±0.1 g/cm3

[ Boiling Point ]:
219.3±23.0 °C at 760 mmHg

[ Melting Point ]:
239 °C (dec.)(lit.)

[ Molecular Formula ]:
CH4N4O2

[ Molecular Weight ]:
104.068

[ Flash Point ]:
86.5±22.6 °C

[ Exact Mass ]:
104.033424

[ PSA ]:
107.72000

[ LogP ]:
-1.31

[ Vapour Pressure ]:
0.1±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.685

[ Water Solubility ]:
3 g/L (20 ºC)

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
MF4600000
CHEMICAL NAME :
Guanidine, 1-nitro-
CAS REGISTRY NUMBER :
556-88-7
LAST UPDATED :
199710
DATA ITEMS CITED :
9
MOLECULAR FORMULA :
C-H4-N4-O2
MOLECULAR WEIGHT :
104.09
WISWESSER LINE NOTATION :
WNMYZUM

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
10200 mg/kg
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - cyanosis
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
3850 mg/kg
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - cyanosis
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
48 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold
TYPE OF TEST :
LD - Lethal dose
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
3120 mg/kg
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - cyanosis

MUTATION DATA

TYPE OF TEST :
Cytogenetic analysis
TEST SYSTEM :
Rodent - hamster Fibroblast
DOSE/DURATION :
4 gm/L/24H
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 48,337,1977

Safety Information

[ Supplemental HS ]:
Explosive when dry.

[ Personal Protective Equipment ]:
Eyeshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
F: Flammable;Xi: Irritant;

[ Risk Phrases ]:
R11;R36/37/38;R5

[ Safety Phrases ]:
S16-S26-S33-S36/37/39-S47-S37/39

[ RIDADR ]:
UN 1336 4.1/PG 1

[ WGK Germany ]:
1

[ RTECS ]:
MF4600000

[ Hazard Class ]:
1.1D

[ HS Code ]:
2925290090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Guanidine nitrate
  • Guanidine sulfate
  • Guanidine thiocyanate
  • Nitroguanylazide
  • 1-Nitrosoguanidine
  • Phosphoric acid
  • Hydrazinecarboximidamide,N-nitro-
  • nitric acid
  • guanidine

DownStream

  • Carbonic acid-guanidine (1:2)
  • 1-Methyl-2-nitroguanidine
  • 1,2-dimethyl-3-nitroguanidine
  • Hydrazinecarboximidamide,N-nitro-
  • Cyanamide
  • Hydrazinecarboximidamide(9CI)
  • 1-Nitrosoguanidine
  • N-Nitroimidazolidin-2-imine
  • Ammonia
  • Hydrazine sulfate

Customs

[ HS Code ]: 2925290090

[ Summary ]:
2925290090 other imines and their derivatives; salts thereof。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles

A novel method for the identification of inorganic and organic gunshot residue particles of lead-free ammunitions from the hands of shooters using scanning laser ablation-ICPMS and Raman micro-spectroscopy.

Analyst 139(23) , 6232-41, (2014)

A method based on scanning laser ablation and inductively coupled plasma-mass spectrometry (SLA-ICPMS) and Raman micro-spectroscopy for the detection and identification of compounds consistent with gu...

Chlorine-free pyrotechnics: copper(I) iodide as a "green" blue-light emitter.

Angew. Chem. Int. Ed. Engl. 53(36) , 9665-8, (2014)

The generation of blue-light-emitting pyrotechnic formulations without the use of chlorine-containing compounds is reported. Suitable blue-light emission has been achieved through the generation of mo...

[Research and determination of occupational exposure limits of nitroguanidine in air of working places].

Zhonghua Lao Dong Wei Sheng Zhi Ye Bing Za Zhi 28(5) , 380-2, (2010)


More Articles

Related Compounds

  • amino-nitroguanidine
  • NETHYLNNITROGUANIDINE
  • Nitroguanidine nitrate
  • N-METHYL NITROGUANIDINE
  • 1-amino-1-nitroguanidine
  • 2-butyl-1-nitroguanidine
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • 7,9-dimethyl-4-{[(1-phenyl-1H-tetrazol-5-yl)methyl]sulfanyl}pyrido[3',2':4,5]thieno[3,2-d]pyrimidine
  • tert-Butyl-DL-alanine
  • 4-amino-N-[2-tert-butyl-1-(tetrahydro-2H-pyran-4-ylmethyl)-1H-benzimidazol-5-yl]-N-ethylbenzenesulfonamide