Diethylzinc

[ Density]:
1.205 g/mL at 25 °C(lit.)

[ Boiling Point ]:
98 °C

[ Melting Point ]:
−28 °C(lit.)

[ Molecular Formula ]:
C₄H₁₀Zn

[ Molecular Weight ]:
123.531

[ Flash Point ]:
45 °F

[ Exact Mass ]:
122.007393

[ LogP ]:
1.94530

[ Index of Refraction ]:
n20/D 1.498(lit.)

[ Water Solubility ]:
REACTS VIOLENTLY

Click to get detail MSDS

[ Symbol ]:

GHS02, GHS05, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H250-H260-H314-H410

[ Supplemental HS ]:
Reacts violently with water.

[ Precautionary Statements ]:
P210-P231 + P232-P280-P305 + P351 + P338-P370 + P378-P422

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F:Flammable;C:Corrosive;N:Dangerousfortheenvironment;

[ Risk Phrases ]:
R11;R14;R17;R34;R48/20;R50/53;R62;R65;R67

[ Safety Phrases ]:
S26-S45-S61-S62-S8-S36/37/39-S16-S60-S43

[ RIDADR ]:
UN 3399 4.3/PG 1

[ WGK Germany ]:
2

[ RTECS ]:
ZH2077777

[ Packaging Group ]:
I

[ Hazard Class ]:
4.3

Click to get detail synthetic route

Precursor

DownStream

Copper-catalyzed asymmetric conjugate addition of diethylzinc to alpha,beta-unsaturated imines derived from alpha-aminoacids. Enantioselective synthesis of gamma-substituted alpha-dehydroaminoesters.

Org. Lett. 8 , 5405, (2006)

[Structure: see text] A highly enantioselective synthesis of alpha-dehydroaminoacids with a stereogenic center in the gamma position through copper-catalyzed asymmetric conjugate addition of diethylzi...

(R)-(+)-Binol-functionalized mesoporous organosilica as a highly efficient pre-chiral catalyst for asymmetric catalysis.

Chem. Asian J. 5(5) , 1232-9, (2010)

(R)-(+)-Binol-functionalized chiral periodic mesoporous organosilicas (PMOs) with different framework compositions were successfully synthesized by cocondensation of (R)-2,2'-di(methoxymethyl)oxy-6,6'...

Highly enantioselective addition of terminal alkynes to aldehydes catalyzed by a new chiral beta-sulfonamide alcohol/Ti(OiPr)4/Et2Zn/R3N catalyst system.

Chirality 21(2) , 316-23, (2009)

A new catalytic system, generated from the readily available and inexpensive beta-sulfonamide alcohol L*, Ti(O(i)Pr)(4), Et(2)Zn, and tertiary amine base (R(3)N), effectively catalyzes the enantiosele...

More Articles