N-TERT-BUTYLTRIMETHYLSILYLAMINE

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Names

[ CAS No. ]:
5577-67-3

[ Name ]:
N-TERT-BUTYLTRIMETHYLSILYLAMINE

[Synonym ]:
N-(Trimethylsilyl)-tert-butylamine
tert-Butylaminotrimethylsilane
MFCD00054891
N-tert-butyl,N-trimethylsilylamine
N-tert-Butyltrimethylsilylamine
N-trimethylsilyl-t-butylamine
tert-butyl-trimethylsilylamine
tert-C4H9NHSi(CH3)3

Chemical & Physical Properties

[ Density]:
0.77g/cm3

[ Boiling Point ]:
118.9ºC at 760mmHg

[ Molecular Formula ]:
C7H19NSi

[ Molecular Weight ]:
145.31800

[ Flash Point ]:
26.7ºC

[ Exact Mass ]:
145.12900

[ PSA ]:
12.03000

[ LogP ]:
2.60030

[ Index of Refraction ]:
n20/D 1.406(lit.)

Safety Information

[ Symbol ]:

GHS02, GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H226-H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C

[ Risk Phrases ]:
10-34

[ Safety Phrases ]:
S16-S26-S45-S36-S37-S39

[ RIDADR ]:
UN 2733 3/PG 3

[ Packaging Group ]:
III

[ Hazard Class ]:
3.2

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Chlorotrimethylsilane
  • tert-Butylamine
  • (tert-butylphosphino)(2,2,6,6-tetramethylpiperidino)boron chloride
  • [tert-butyl(trimethylsilyl)amino]lithium
  • chloro{(di-tert-butylphosphanyl)amino}(2,2,6,6-tetramethylpiperidino)borane
  • 4-Picoline

DownStream

  • Propanamide,N-(1,1-dimethylethyl)-
  • Diethylsilane
  • ethyl(methyl)silane
  • N-(dimethylsilyl)-1,1,1-trimethylsilanamine
  • trimethylsilylurea
  • Acetamide,N-(1,1-dimethylethyl)-
  • Benzamide,N-(1,1-dimethylethyl)-
  • 4-Picoline
  • [tert-butyl(trimethylsilyl)amino]lithium

Articles

Azido- or hydroxyl-capped half-cubanes containing Cp*Rh fragments: [Cp*3Rh3(mu-X)3(mu3-X)]2+ (X-=OH- or N3-).

Dalton Trans. (20) , 3360-4, (2004)

Treatment of [Cp*Rh(H(2)O)(3)](OTf)(2) (1) with Me(3)SiNH-t-Bu in acetone gave a hydroxyl-capped half-cubane [Cp*(3)Rh(3)(mu-OH)(3)(mu(3)-OH)](OTf)(3)(t-BuNH(3)) (2). Slow diffusion of Me(3)SiN(3) in ...

J. Solid State Inorg. Chem. 29 , 759, (1992)

Synth. Commun. 21 , 201, (1991)


More Articles

Related Compounds

  • tert-butyl (3R)-3-[(propylamino)methyl]piperidine-1-carboxylate
  • 5-bromo-1-(tetrahydro-2H-pyran-2-yl)-1H-Thieno[3,2-c]pyrazole
  • Rel-2-(3-((2R,5R)-4-methoxy-5-methylpiperidin-2-yl)phenoxy)-N,N-dimethylethan-1-amine
  • N-ethyl-6-methyl-2-{4-[2-(4-methyl-1H-pyrazol-1-yl)ethyl]piperazin-1-yl}pyrimidin-4-amine
  • N-[1-(3-fluoropyridin-2-yl)piperidin-3-yl]cyclopropanesulfonamide
  • N-[1-(6-methylpyridin-2-yl)piperidin-3-yl]cyclopropanesulfonamide
  • 1-(5-Bromo-3-chloropyridin-2-yl)-4-(cyclopropanesulfonyl)-1,4-diazepane
  • 2-(2-Methoxyethyl)-5-(5-methyl-3,4,5,6-tetrahydropyridin-2-yl)benzo[d]thiazole
  • tert-Butyl 5-methyl-5,6-dihydro-[2,3'-bipyridine]-1(4H)-carboxylate
  • tert-Butyl 1',5-dimethyl-1',2',3',5,6,6'-hexahydro-[2,4'-bipyridine]-1(4H)-carboxylate
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