N-TERT-BUTYLTRIMETHYLSILYLAMINE

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Names

[ CAS No. ]:
5577-67-3

[ Name ]:
N-TERT-BUTYLTRIMETHYLSILYLAMINE

[Synonym ]:
N-(Trimethylsilyl)-tert-butylamine
tert-Butylaminotrimethylsilane
MFCD00054891
N-tert-butyl,N-trimethylsilylamine
N-tert-Butyltrimethylsilylamine
N-trimethylsilyl-t-butylamine
tert-butyl-trimethylsilylamine
tert-C4H9NHSi(CH3)3

Chemical & Physical Properties

[ Density]:
0.77g/cm3

[ Boiling Point ]:
118.9ºC at 760mmHg

[ Molecular Formula ]:
C7H19NSi

[ Molecular Weight ]:
145.31800

[ Flash Point ]:
26.7ºC

[ Exact Mass ]:
145.12900

[ PSA ]:
12.03000

[ LogP ]:
2.60030

[ Index of Refraction ]:
n20/D 1.406(lit.)

Safety Information

[ Symbol ]:

GHS02, GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H226-H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C

[ Risk Phrases ]:
10-34

[ Safety Phrases ]:
S16-S26-S45-S36-S37-S39

[ RIDADR ]:
UN 2733 3/PG 3

[ Packaging Group ]:
III

[ Hazard Class ]:
3.2

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Chlorotrimethylsilane
  • tert-Butylamine
  • (tert-butylphosphino)(2,2,6,6-tetramethylpiperidino)boron chloride
  • [tert-butyl(trimethylsilyl)amino]lithium
  • chloro{(di-tert-butylphosphanyl)amino}(2,2,6,6-tetramethylpiperidino)borane
  • 4-Picoline

DownStream

  • Propanamide,N-(1,1-dimethylethyl)-
  • Diethylsilane
  • ethyl(methyl)silane
  • N-(dimethylsilyl)-1,1,1-trimethylsilanamine
  • trimethylsilylurea
  • Acetamide,N-(1,1-dimethylethyl)-
  • Benzamide,N-(1,1-dimethylethyl)-
  • 4-Picoline
  • [tert-butyl(trimethylsilyl)amino]lithium

Articles

Azido- or hydroxyl-capped half-cubanes containing Cp*Rh fragments: [Cp*3Rh3(mu-X)3(mu3-X)]2+ (X-=OH- or N3-).

Dalton Trans. (20) , 3360-4, (2004)

Treatment of [Cp*Rh(H(2)O)(3)](OTf)(2) (1) with Me(3)SiNH-t-Bu in acetone gave a hydroxyl-capped half-cubane [Cp*(3)Rh(3)(mu-OH)(3)(mu(3)-OH)](OTf)(3)(t-BuNH(3)) (2). Slow diffusion of Me(3)SiN(3) in ...

J. Solid State Inorg. Chem. 29 , 759, (1992)

Synth. Commun. 21 , 201, (1991)


More Articles

Related Compounds

  • 1-[1-(trifluoromethyl)-1H-pyrazol-5-yl]cyclopropane-1-carboxylic acid
  • (9H-fluoren-9-yl)methyl N-[4-(prop-2-yn-1-yloxy)phenyl]carbamate
  • (9H-fluoren-9-yl)methyl N-[9-(prop-2-yn-1-yl)-9H-purin-6-yl]carbamate
  • benzyl N-(3-hydroxy-3-methylbutyl)-N-methylcarbamate
  • 3-Formyl-2-(2,2,2-trifluoroacetamido)benzoic acid
  • 5-({[(Prop-2-en-1-yloxy)carbonyl]amino}methyl)naphthalene-1-carboxylic acid
  • 6-Cyano-2-[(prop-2-en-1-yloxy)carbonyl]-1,2,3,4-tetrahydroisoquinoline-1-carboxylic acid
  • (2S)-4-(3-methyl-3H-diazirin-3-yl)-2-{[(prop-2-en-1-yloxy)carbonyl]amino}butanoic acid
  • 1-(trifluoromethyl)-1H-1,3-benzodiazole-2-carbaldehyde
  • 2-(2-Methylbut-3-yn-2-yl)-5-(trifluoromethyl)furan
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