Terabutyl titanate

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Names

[ Name ]:
Terabutyl titanate

[Synonym ]:
Titanium(2+) 1-butanolate (1:2)
BUTYL TITANATE
Tyzor BP
VERTEC(TM) TNBT
tetra-n-butyl titanate
titanium(IV) n-butoxide
TNBT
titaniuM salt
titanium tetra-n-butoxide
titanium(IV) tetra(n-butoxide)
tyzortbt
orgaticsta25
b1(titanate)
EINECS 227-006-8
1-Butanol, titanium(2+) salt (2:1)
MFCD00009433
Ti(OCH2CH2CH2CH3)4
Titanium Butoxide
Terabutyl titanate

Chemical & Physical Properties

[ Density]:
1.00 g/mL at 20 °C(lit.)

[ Boiling Point ]:
206 °C10 mm Hg(lit.)

[ Melting Point ]:
-55°C

[ Molecular Formula ]:
C₁₆H₃₆O₄Ti₂

[ Molecular Weight ]:
388.189

[ Flash Point ]:
55 °F

[ Exact Mass ]:
388.157257

[ PSA ]:
36.92000

[ LogP ]:
5.06960

[ Index of Refraction ]:
n20/D 1.491(lit.)

[ Stability ]:
Stable, but moisture sensitive. Flammable. Incompatible with water, moisture, strong oxidizing agents, strong acids.

[ Water Solubility ]:
RAPIDLY HYDROLIZED

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: XR1585000

CHEMICAL NAME :: Titanic acid, tetrabutyl ester

CAS REGISTRY NUMBER :: 5593-70-4

LAST UPDATED :: 199710

DATA ITEMS CITED :: 6

MOLECULAR FORMULA :: C16-H36-O4.Ti

MOLECULAR WEIGHT :: 340.42

WISWESSER LINE NOTATION :: 4O-TI-O4&O4&O4

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 3122 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1263,1986

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 180 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#01650 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M0833 No. of Facilities: 248 (estimated) No. of Industries: 8 No. of Occupations: 30 No. of Employees: 8950 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M0833 No. of Facilities: 1979 (estimated) No. of Industries: 28 No. of Occupations: 32 No. of Employees: 26386 (estimated) No. of Female Employees: 5431 (estimated)

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H226-H315-H318-H335-H336

[ Precautionary Statements ]:
P280-P305 + P351 + P338 + P310-P403 + P235

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S16-S26-S39-S24/25

[ RIDADR ]:
UN 1993 3/PG 3

[ WGK Germany ]:
1

[ RTECS ]:
XR1585000

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
29051900

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

BUTOXYTRIMETHYLSILANE
Hexamethyldisiloxane
Acetic acid,2,2,2-trifluoro-, butyl ester
Monobutyl maleate
Carbamic acid,N-phenyl-, butyl ester
Benzenamine,N,N'-methanetetraylbis-
butyl N-phenyl-N-(phenylcarbamoyl)carbamate
butyl acetate
1-Naphthalenecarboxylicacid, butyl ester

Customs

[ HS Code ]: 29051900

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