2-Hydroxy-3a,4,7,7a-tetrahydro-1H-4,7-epoxyisoindole-1,3(2H)-dione

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Names

[ Name ]:
2-Hydroxy-3a,4,7,7a-tetrahydro-1H-4,7-epoxyisoindole-1,3(2H)-dione

[Synonym ]:
4,7-Epoxy-1H-isoindole-1,3(2H)-dione, 3a,4,7,7a-tetrahydro-2-hydroxy-, (3aR,4S,7R,7aS)-
(1R,2S,6R,7S)-4-Hydroxy-10-oxa-4-azatricyclo[5.2.1.0]dec-8-ene-3,5-dione
MFCD00180244
Exo-N-hydroxy-7-oxabicyclo[2.2.1]hept-5-ene-2,3-dicarboximide
(3aR,4S,7R,7aS)-2-Hydroxy-3a,4,7,7a-tetrahydro-1H-4,7-epoxyisoindole-1,3-dione

Chemical & Physical Properties

[ Density]:
1.7±0.1 g/cm3

[ Boiling Point ]:
384.8±52.0 °C at 760 mmHg

[ Melting Point ]:
194ºC (dec.)(lit.)

[ Molecular Formula ]:
C₈H₇NO₄

[ Molecular Weight ]:
181.145

[ Flash Point ]:
186.5±30.7 °C

[ Exact Mass ]:
181.037506

[ PSA ]:
66.84000

[ LogP ]:
-1.47

[ Vapour Pressure ]:
0.0±2.0 mmHg at 25°C

[ Index of Refraction ]:
1.680

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37-S39

[ RIDADR ]:
NONH for all modes of transport

[ HS Code ]:
2925190090

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2925190090

[ Summary ]:
2925190090 other imides and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

Fluorous tagged N-hydroxy phthalimide for the parallel synthesis of O-aryloxyamines.

J. Comb. Chem. 12 , 655-658, (2010)

The parallel synthesis of O-aryloxyamines remains an unfulfilled need in the field of medicinal chemistry and fragment-based approaches. To fill this gap a solution-phase two-step process based on (1)...

(2S)-4-[4-methyl-3-(trifluoromethyl)phenyl]butan-2-ol
1,3-dioxo-2,3-dihydro-1H-isoindol-2-yl 3-methyl-1-(2-methylpropyl)-2,4-dioxo-1H,2H,3H,4H-pyrido[2,3-d]pyrimidine-6-carboxylate
4-[4-Methyl-3-(trifluoromethyl)phenyl]oxane-2,6-dione
rac-1,3-dioxo-2,3-dihydro-1H-isoindol-2-yl (1R,3S)-3-carbamoylcyclopentane-1-carboxylate
3-[(3,4-Dichlorophenyl)methyl]oxetan-3-ol
3-(4-Ethylcyclohexyl)-1,1,1-trifluoropropan-2-amine
3-(1,5-dimethyl-1H-pyrazol-4-yl)-4,4-difluorobutanoic acid
1-{[3-fluoro-4-(trifluoromethyl)phenyl]methyl}-N-methylcyclopropan-1-amine
5-[3-Fluoro-4-(trifluoromethyl)phenyl]-1,3-oxazolidin-2-one
rac-1-(1,3-dioxo-2,3-dihydro-1H-isoindol-2-yl) 3-ethyl (1R,3S)-cyclopentane-1,3-dicarboxylate

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