Bicyclo[2.2.1]heptan-2-one,3-methylene-

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Names

[ CAS No. ]:
5597-27-3

[ Name ]:
Bicyclo[2.2.1]heptan-2-one,3-methylene-

[Synonym ]:
2-methylidenebicyclo[2.2.1]heptan-3-one
MFCD00151643
EINECS 227-009-4

Chemical & Physical Properties

[ Density]:
0.997 g/mL at 25ºC(lit.)

[ Boiling Point ]:
69-71ºC11 mm Hg(lit.)

[ Melting Point ]:
69-71ºC

[ Molecular Formula ]:
C8H10O

[ Molecular Weight ]:
122.16400

[ Flash Point ]:
131 °F

[ Exact Mass ]:
122.07300

[ PSA ]:
17.07000

[ LogP ]:
1.54160

[ Index of Refraction ]:
n20/D 1.493(lit.)

MSDS

Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Risk Phrases ]:
R10

[ Safety Phrases ]:
S16

[ RIDADR ]:
UN 1224 3/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3.2

[ HS Code ]:
2914299000

Synthetic Route

Precursor & DownStream

Precursor

  • 3-((diethylamino)methyl)bicyclo[2.2.1]heptan-2-one
  • exo-3-Hydroxy-2-methylennorbornan
  • NORCAMPHOR
  • Norbornane, 2-methylene-
  • Bicyclo[2.2.1]hept-2-ene,2-methyl-
  • Formaldehyde

DownStream

  • spiro[bicyclo[2.2.1]heptane-3,1'-cyclopropane]-2-one
  • 2-(2,2-dimethylpropyl)bicyclo[2.2.1]heptan-3-one

Customs

[ HS Code ]: 2914299000

[ Summary ]:
2914299000. other cyclanic, cyclenic or cyclotherpenic ketones without other oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

Inhibitory effects of monoterpenes on human TRPA1 and the structural basis of their activity.

J. Physiol. Sci. 64 , 47-57, (2014)

TRPA1, one of the transient receptor potential channels, has been reported to be involved in nociception and inflammatory pain, suggesting that this molecule could be a promising target for the develo...


More Articles


Related Compounds

  • Bicyclo[2.2.1]heptan-2-one,3-[[bis(2-chloroethyl)amino]methylene]-
  • Bicyclo[2.2.1]heptan-2-one, 3-acetyl-1,7,7-trimethyl-, (1R,3R,4R)- (9CI)
  • Bicyclo[2.2.1]heptan-2-one, 3-acetyl-1,7,7-trimethyl-, (1R,4R)- (9CI)
  • Bicyclo[2.2.1]heptan-2-one,3-(aminomethylene)-1,7,7-trimethyl-
  • Bicyclo[2.2.1]heptan-2-one,3-amino-1,7,7-trimethyl-, hydrochloride (1:1)
  • Bicyclo[2.2.1]heptan-2-one, 3-[(1R)-1-methyl-2-nitroethyl]-, (1S,3R,4R)-rel- (9CI)