3-Oxabicyclo[3.1.0]hexane-2,4-dione

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Names

[ CAS No. ]:
5617-74-3

[ Name ]:
3-Oxabicyclo[3.1.0]hexane-2,4-dione

[Synonym ]:
cyclopropanedicarboxylic anhydride
Cyclopropan-1,2-dicarbonsaeure-anhydrid
methanosuccinic anhydride
oxabicyclohexanedione
1,2-cyclopropanedicarboxylic anhydride
3-Oxabicyclo[3.1.0]hexane-2,4-dione
cyclopropane-1,2-dicarboxylic acid anhydride
MFCD00126929

Chemical & Physical Properties

[ Density]:
1.6±0.1 g/cm3

[ Boiling Point ]:
280.5±9.0 °C at 760 mmHg

[ Melting Point ]:
59-61ºC(lit.)

[ Molecular Formula ]:
C5H4O3

[ Molecular Weight ]:
112.084

[ Flash Point ]:
143.3±15.9 °C

[ Exact Mass ]:
112.016045

[ PSA ]:
43.37000

[ LogP ]:
-1.45

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.556

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
37/39-26

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2917209090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 1,2-Cyclopropanedicarboxylicacid
  • cyclopropane-1,1,2-tricarboxylic acid
  • tetraethyl cyclopropane-1,1,2,2-tetracarboxylate
  • (+/-)-trans-1,2-Cyclopropanedicarboxylic acid
  • cyclopropane-1,1,2,2-tetracarboxylic acid
  • Aethylmethyl-1,2-cyclopropandicarboxylat
  • DIETHYL 1,2-CYCLOPROPANEDICARBOXYLATE
  • (CIS)-CYCLOPROPANE-1,2-DICARBOXYLIC ACID
  • CIS-DIETHYL CYCLOPROPANE-1,2-DICARBOXYLATE

DownStream

  • 3-hydroxy-3-azabicyclo[3.1.0]hexane
  • Cis-Dimethyl Cyclopropane-1,2-Dicarboxylate
  • CIS-DIETHYL CYCLOPROPANE-1,2-DICARBOXYLATE
  • 3-Benzyl-3-azabicyclo[3.1.0]hexane
  • 3-Benzyl-3-azabicyclo[3.1.0]hexane-2,4-dione
  • 1,1-cyclopropanedicarboxylic acid monoethyl ester
  • Cyclopropanecarboxylicacid, 2-benzoyl-, cis- (8CI,9CI)
  • ETHYL4-(4,4-DIMETHYL-2,6-DIOXOPIPERIDIN-1-YL)BENZOATE
  • (CIS)-CYCLOPROPANE-1,2-DICARBOXYLIC ACID

Customs

[ HS Code ]: 2917209090

[ Summary ]:
2917209090 other cyclanic, cyclenic or cyclotherpenic polycarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

Related Compounds

  • 1-Amino-3-oxabicyclo[3.1.0]hexane-2,4-dione
  • 1-phenyl-3-oxabicyclo[3.1.0]hexane-2,4-dione
  • 6,6-Dimethyl-3-oxabicyclo[3.1.0]hexane-2,4-dione
  • 1,5-dimethyl-3-oxabicyclo[3.1.0]hexane-2,4-dione
  • (1R)-1-phenyl-3-oxabicyclo[3.1.0]hexane-2,4-dione
  • 1-bromo-5-methyl-3-oxabicyclo[3.1.0]hexane-2,4-dione
  • 1-[4-(4-Methylpyrrolidin-3-yl)-1,4-diazepan-1-yl]ethan-1-one
  • 2-Methoxy-1-(oxan-3-yl)ethan-1-one
  • 1-ethyl-3-(trifluoromethyl)-4,5,6,7-tetrahydro-1H-indazole
  • 5-Bromo-2-(4-Chlorophenyl)-1H-Indole-3-Propanoic Acid
  • (2R,3S)-2,3-Bis(4-chlorophenyl)-1,4-dioxane
  • methyl 2-(7-methoxy-2,3-dihydro-1H-inden-4-yl)acetate
  • 2-(7-methoxy-2,3-dihydro-1H-inden-4-yl)acetic acid
  • 1-[(4-cyanophenyl)methyl]-1H-pyrrole-2-carboxylic acid
  • methyl 3-(1-acetyl-1H-indazol-5-yl)-3-oxopropanoate
  • 1-(4-Hydroxyphenyl)-1,2,4a,5,6,7,8,8a-octahydrochromeno[2,3-c]pyrrole-3,9-dione
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