Bromonitromethane

Names

[ CAS No. ]:
563-70-2

[ Name ]:
Bromonitromethane

[Synonym ]:
MFCD00007401
EINECS 209-258-0
bromo(nitro)methane

Chemical & Physical Properties

[ Density]:
2.07

[ Boiling Point ]:
146-148 °C (750 mmHg)

[ Molecular Formula ]:
CH₂BrNO₂

[ Molecular Weight ]:
139.93600

[ Flash Point ]:
4°C

[ Exact Mass ]:
138.92700

[ PSA ]:
45.82000

[ LogP ]:
1.13870

[ Index of Refraction ]:
1.485-1.495

MSDS

Safety Information

[ Symbol ]:

GHS03, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H272-H315-H319-H335

[ Precautionary Statements ]:
P220-P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
O: Oxidizing agent;Xn: Harmful;

[ Risk Phrases ]:
R8;R36/37/38

[ Safety Phrases ]:
S36/37/39-S26-S17-S36

[ RIDADR ]:
3098

[ RTECS ]:
PA5360000

[ Packaging Group ]:
III

[ Hazard Class ]:
5.1

[ HS Code ]:
2904909090

Synthetic Route

Click to get detail synthetic route

Customs

[ HS Code ]: 2904909090

[ Summary ]:
HS:2904909090 sulphonated, nitrated or nitrosated derivatives of hydrocarbons, whether or not halogenated VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Silyl imine electrophiles in enantioselective catalysis: a Rosetta Stone for peptide homologation, enabling diverse N-protected aryl glycines from aldehydes in three steps.

Org. Lett. , (2014)

We report that N-(trimethylsilyl)imines serve in the Bis(AMidine)-catalyzed addition of bromonitromethane with a high degree of enantioselection. This allows for the production of a range of protected...

Stereoselective synthesis of highly functionalized nitrocyclopropanes through the organocatalyic Michael-addition-initiated cyclization of bromonitromethane and β,γ-unsaturated α-ketoesters.

Chem. Asian J. 8(11) , 2859-63, (2013)

A highly diastereo- and enantioselective cyclopropanation of β,γ-unsaturated α-ketoesters with bromonitromethane has been successfully developed through a domino Michael-addition/intramolecular-alkyla...

Synthesis of enantiopure 2-C-glycosyl-3-nitrochromenes.

J. Org. Chem. 78(24) , 12831-6, (2013)

A novel methodology has been developed to obtain enantiopure 2-C-glycosyl-3-nitrochromenes. First, (Z)-1-bromo-1-nitroalkenes were prepared from the corresponding sugar aldehydes through a sodium iodi...

2-bromonitromethane
N,N-dimethyl-6-(4-{2-methylpyrazolo[1,5-a]pyrazin-4-yl}piperazin-1-yl)pyrimidin-4-amine
6-Chloro-2-(3-{octahydrocyclopenta[c]pyrrol-2-yl}azetidin-1-yl)-1,3-benzoxazole
4-{2-Cyclopropylpyrazolo[1,5-a]pyrazin-4-yl}-2-(pyrrolidine-1-carbonyl)morpholine
5-chloro-N-[1-(cyclopropanesulfonyl)piperidin-4-yl]-N-methylpyrimidin-2-amine
2-{4-[4-methyl-6-(morpholin-4-yl)pyrimidin-2-yl]piperazin-1-yl}-5H,6H,7H-cyclopenta[b]pyridine-3-carbonitrile
2-{4-[2-methyl-6-(morpholin-4-yl)pyrimidin-4-yl]piperazin-1-yl}-5H,6H,7H-cyclopenta[b]pyridine-3-carbonitrile
2-methyl-1-[(1-{2-methylpyrazolo[1,5-a]pyrazin-4-yl}azetidin-3-yl)methyl]-1H-imidazole
4-({methyl[4-(trifluoromethyl)pyridin-2-yl]amino}methyl)-N-(oxan-4-yl)piperidine-1-carboxamide
2-(5-Chloro-2-methylphenyl)-1,1-dioxo-4-prop-2-ynyl-1lambda6,2,4-benzothiadiazin-3-one
N,N-dimethyl-2-(4-{pyrazolo[1,5-a]pyrazin-4-yl}piperazin-1-yl)pyrimidin-4-amine

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