D-Plenylglycinol

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Names

[ Name ]:
D-Plenylglycinol

[Synonym ]:
Benzeneethanol, β-amino-, (βS)-
(S)-2-Amino-1-phenylethanol
H-PHENYLGLYCINOL
(2S)-Phenylglycinol
(2S)-2-amino-2-phenyl-1-ethanol
Benzeneethanol, β-amino-, (S)-
EINECS 260-287-5
MFCD00008062
H-PHG-OL
L-2-PHENYLGLYCINOL
(S)-Phenylglycinol
(S)-2-Phenylglycinol
(S)-2-hydroxy-1-phenylethylamine
(S)-2-Amino-2-phenylethanol
(S)-(+)-2-Amino-2-phenylethanol
(S)-(+)-2-Phenylglycinol
L-Phenylglycinol
PHENYLGLYCINOL(L-)
L-Plenylglycinol
(2S)-2-Amino-2-phenylethanol
L-(+)-α-Phenylglycinol
(S)-1-phenyl-2-hydroxyethylamine
H-L-PHG-OL
D-Plenylglycinol
D-Phg-ol
D-2-phenylglycinol

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
261.0±0.0 °C at 760 mmHg

[ Melting Point ]:
76-79 °C

[ Molecular Formula ]:
C₈H₁₁NO

[ Molecular Weight ]:
137.18

[ Flash Point ]:
125.3±21.8 °C

[ Exact Mass ]:
137.084061

[ PSA ]:
46.25000

[ LogP ]:
0.42

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.572

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
T: Toxic;C: Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S22-S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2922199090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

D-2-Phenylglycine
N-Phenylglycine
methyl (R)-aminophenylacetate
N-[(1R)-2-hydroxy-1-phenylethyl]acetamide
(S)-(+)-2-Phenylglycinol
Ethyl (3S)-3-amino-3-phenylpropanoate
(R)-ALPHA-BENZYL-L-PROLINE-HCL
(RS,1R)-2-methylpropane-2-sulfinic acid [1-((tert-butyldimethylsilanyloxy)methyl)-1-phenylethyl]amide

DownStream

(R)-3-Phenylpiperidine
1-[1-(benzenesulfonyl)-3-methylindol-2-yl]ethanone
(R)-(+)-1-Phenylethylamine
L-1-Phenylethylamine
(R)-4-Phenyloxazolidin-2-one
(R)-N-(2-hydroxy-1-phenylethyl)-4-methylbenzenesulfonamide
BOC-L-Phenylglycinol
(4R)-2,4-diphenyl-4,5-dihydro-1,3-oxazole
2,5-diphenyl-4,5-dihydro-1,3-oxazole

Customs

[ HS Code ]: 2922199090

[ Summary ]:
2922199090. other amino-alcohols, other than those containing more than one kind of oxygen function, their ethers and esters; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Straightforward synthesis of (S)- and (R)-alpha-trifluoromethyl proline from chiral oxazolidines derived from ethyl trifluoropyruvate.

Org. Lett. 8 , 6123, (2006)

[Structure: see text] A concise synthesis of both enantiomers of alpha-Tfm-proline and (S)-alpha-Tfm-prolinol from ethyl trifluoropyruvate is reported. The key step is a diastereoselective allylation ...

Amedjkouh, M.; Westerlund, K.

Tetrahedron Lett. 45 , 5175, (2004)

Tetrahedron Lett. 45 , 5287, (2004)

D-Plenylglycinol
D-Galactitol, 3,6-anhydro-2-O-methyl-, triacetate
D-(tetrahydro-2,3,4-trihydroxy-5-oxofuran-2-yl)glycollic acid
D-HOMOCYSTEINESULFINIC ACID
D-allo-Heptose, 2,6-anhydro-4-deoxy-3-O-methyl-5-O-(phenylmethyl)-, 7-acetate
D-3263
4-(1-(2-(2-chlorophenoxy)ethyl)-1H-benzo[d]imidazol-2-yl)-1-(p-tolyl)pyrrolidin-2-one
4-(1-(2-(3-methoxyphenoxy)ethyl)-1H-benzo[d]imidazol-2-yl)-1-(p-tolyl)pyrrolidin-2-one
4-Bromo-1-(3,4-dihydro-1H-isoquinolin-2-yl)butan-1-one
2-{2-[1-(4-methylphenyl)-5-oxopyrrolidin-3-yl]-1H-1,3-benzodiazol-1-yl}-N,N-dipropylacetamide
1-(4-methylphenyl)-4-{1-[2-oxo-2-(1-pyrrolidinyl)ethyl]-1H-benzimidazol-2-yl}-2-pyrrolidinone
1-(4-methylphenyl)-4-{1-[2-oxo-2-(piperidin-1-yl)ethyl]-1H-1,3-benzodiazol-2-yl}pyrrolidin-2-one
Methyl 2-{2-[1-(4-methylphenyl)-5-oxopyrrolidin-3-yl]benzimidazolyl}acetate
2-Hydroxymethyl-1,4-dithiane
4-Methoxy-2,3,5-trimethylaniline
1-Cyclohexyl-2,3-dimethoxybenzene

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