Ethyl phthalimidomalonate

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Names

[ CAS No. ]:
5680-61-5

[ Name ]:
Ethyl phthalimidomalonate

[Synonym ]:
Phthalimido-malonsaeure-diaethylester
MFCD00065025
phthalimido-malonic acid diethyl ester
Diethyl (1,3-dioxo-1,3-dihydro-2H-isoindol-2-yl)malonate
Ethyl phthalimidomalonate
2-Isoindolinemalonic acid,1,3-dioxo-,diethyl ester
EINECS 227-138-6
Propanedioic acid, (1,3-dihydro-1,3-dioxo-2H-isoindol-2-yl)-, diethyl ester
Diethyl 2-phthalimidomalonate
Propanedioic acid, 2-(1,3-dihydro-1,3-dioxo-2H-isoindol-2-yl)-, diethyl ester
Malonic acid,phthaliMido-,diethyl ester
DIETHYL PHTHALIMIDOMALONATE

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
425.3±35.0 °C at 760 mmHg

[ Melting Point ]:
73-76 °C(lit.)

[ Molecular Formula ]:
C15H15NO6

[ Molecular Weight ]:
305.283

[ Flash Point ]:
211.0±25.9 °C

[ Exact Mass ]:
305.089935

[ PSA ]:
89.98000

[ LogP ]:
3.21

[ Vapour Pressure ]:
0.0±1.0 mmHg at 25°C

[ Index of Refraction ]:
1.560

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Potassium phthalimide
  • ethyl bromomalonate
  • Diethyl malonate
  • 2-Bromo-1H-isoindole-1,3(2H)-dione
  • sodium 1,3-diethoxy-1,3-dioxopropan-2-ide
  • Diethyl ether
  • Ethanol

DownStream

  • α-Aminoadipic acid
  • N-Phthaloylglycine
  • APM
  • DL-Glutamic acid
  • 5-amino-2-sulfanylidene-1,3-diazinane-4,6-dione

Articles

Potentiometric detection of Cr 3+ ions in solution by a chromium (III) electrochemical sensor based on diethyl 2-phthalimidomalonate doped in polymeric membrane. Zamani HA and Sahebnasagh S.

Int. J. Electrochem. Sci. 8 , 3708-20, (2013)

Evidence for nc. far.. pi.* transition in N-malonic esters of heterocyclic compounds. Nnadi JC and Wang SY.

J. Am. Chem. Soc. 92(14) , 4421-25, (1970)


More Articles

Related Compounds

  • ethyl 8-(4-fluorophenyl)-8-oxooctanoate
  • ETHYL 4-(3,4-DIMETHYLPHENYL)-4-OXOBUTYRATE
  • ethyl 3-(3-nitrophenyl)-4-oxopent-2-enoate
  • ETHYL 8-(1-NAPHTHYL)-8-OXOOCTANOATE
  • ETHYL 2-((TERT-BUTOXYCARBONYL)AMINO)THIAZOLE-5-CARBOXYLATE
  • ETHYL MORPHOLINE-2-CARBOXYLATE HYDROCHLORIDE