disulphur decafluoride

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Names

[ CAS No. ]:
5714-22-7

[ Name ]:
disulphur decafluoride

[Synonym ]:
TL 70
DISULFUR DECAFLUORIDE
Sulfur pentafluoride
Disulphur decafluoride
EINECS 227-204-4
Sulfur decafluoride

Chemical & Physical Properties

[ Boiling Point ]:
29ºC

[ Melting Point ]:
-55ºC

[ Molecular Formula ]:
F10S2

[ Molecular Weight ]:
254.11400

[ Exact Mass ]:
253.92800

[ PSA ]:
50.60000

[ LogP ]:
5.49840

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
WS4480000
CHEMICAL NAME :
Sulfur decafluoride
CAS REGISTRY NUMBER :
5714-22-7
LAST UPDATED :
199712
DATA ITEMS CITED :
22
MOLECULAR FORMULA :
F10-S2
MOLECULAR WEIGHT :
254.12
WISWESSER LINE NOTATION :
FSFFFF 2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
45 gm/m3/10M
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: PB158-508
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Mammal - dog
DOSE/DURATION :
1 mg/kg
TOXIC EFFECTS :
Vascular - shock Lungs, Thorax, or Respiration - acute pulmonary edema Blood - changes in cell count (unspecified)
REFERENCE :
AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 8,436,1953
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
5790 ug/kg
REFERENCE :
AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 8,436,1953 *** REVIEWS *** ACGIH TLV-CL 0.10 mg/m3 (0.01 ppm) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.025 ppm (0.25 mg/m3) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,241,1971 OSHA PEL (Gen Indu):8H TWA 0.025 ppm (0.25 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.025 ppm (0.25 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.025 ppm (0.25 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.025 ppm (0.25 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 0.01 ppm (0.1 mg/m3) JAN 1993 OEL-BELGIUM:STEL 0.01 ppm (0.1 mg/m3) JAN 1993 OEL-DENMARK:TWA 0.025 ppm (0.25 mg/m3) JAN 1993 OEL-FINLAND:TWA 0.025 ppm (0.25 mg/m3);STEL 0.075 ppm ;Skin JAN 1993 OEL-GERMANY:TWA 0.025 ppm (0.25 mg/m3) JAN 1993 OEL-THE NETHERLANDS:TWA 0.01 ppm (0.1 mg/m3) JAN 1993 OEL-THE PHILIPPINES:TWA 0.025 ppm (0.25 mg/m3) JAN 1993 OEL-SWITZERLAND:TWA 0.01 ppm (0.1 mg/m3);STEL 0.02 ppm JAN 1993 OEL-TURKEY:TWA 0.025 ppm (0.25 mg/m3) JAN 1993 OEL-UNITED KINGDOM:TWA 0.025 ppm (0.25 mg/m3);STEL 0.075 ppm JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO SULFUR PENTAFLUORIDE-air:CL 0.01 ppm REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992

Safety Information

[ Hazard Codes ]:
T

[ Risk Phrases ]:
26/27/28-34

[ Safety Phrases ]:
26-36/37/39-45

[ RIDADR ]:
UN 3287

[ Packaging Group ]:
I

[ Hazard Class ]:
6.1(a)

Synthetic Route

Precursor & DownStream

Precursor

  • Fluorine
  • Sulfur
  • sulphur chloropentafluoride
  • Sulfur hexafluoride
  • SULFUR BROMOPENTAFLUORIDE
  • nitrogen dioxide
  • {1,2-difluoro-1,2-bis(trifluoromethyl)-1,2-ethanediyl}bis(pentafluorosulfur(VI))
  • 1,1,2-trifluoro-2-pentafluorosulfanylethene

DownStream

  • sulfur(+2) tetrahydride cation tetrafluoride
  • Sulfur hexafluoride
  • pentafluorosulfur fluorosulfonate
  • Sulfur trioxide
  • thionyl fluoride
  • SULFUR BROMOPENTAFLUORIDE
  • trifluoro-nitro-methane
  • sulphur chloropentafluoride
  • HYDROFLUORIC ACID

Related Compounds

  • Tellurium decafluoride
  • hypobromous dithioperoxyanhydride
  • lithium,erbium(3+),thulium(3+),yttrium(3+),decafluoride
  • (trifluoro-λ4-sulfanyl) thiohypofluorite
  • Diatomic sulfur
  • DISULFURYL FLUORIDEDISCONTINUED WHEN STOCK SOLD 4/10/00
  • 2-{1-[(pyrimidin-4-yl)methyl]-1H-1,3-benzodiazol-2-yl}ethan-1-amine
  • 3-(2-amino-5-methyl-1H-imidazol-4-yl)-1-phenylpropan-1-one
  • 4-(2,2-dimethylcyclopropyl)-4-ethyl-3H,4H,5H,6H,7H-imidazo[4,5-c]pyridine
  • 3-Methanesulfonyl-3',5',6',7'-tetrahydrospiro[cyclobutane-1,4'-imidazo[4,5-c]pyridine]
  • tert-butyl 5-(piperazin-2-yl)-1H-1,2,3-triazole-4-carboxylate
  • 5-butyl-4-(2,2-dimethylpropyl)-4H-1,2,4-triazole-3-thiol
  • 4-cyclopentyl-5-hexyl-4H-1,2,4-triazole-3-thiol
  • methyl 2-[3-(2,2-dimethylpropyl)-5-sulfanyl-4H-1,2,4-triazol-4-yl]acetate
  • 5-(methoxymethyl)-4-(2,2,2-trifluoroethyl)-4H-1,2,4-triazole-3-thiol
  • 4-nitro-N-({octahydro-1H-pyrido[1,2-a]pyrazin-3-yl}methyl)benzene-1-sulfonamide
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